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A Series of Green Oxovanadium(IV) Precatalysts with O, N and S Donor Ligands in a Sustainable Olefins Oligomerization Process

Designing catalyst systems based on transition metal ions and activators using the principles of green chemistry is a fundamental research goal of scientists due to the reduction of poisonous solvents, metal salts and organic ligands released into the environment. Urgent measures to reduce climate c...

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Autores principales: Urbaniak, Mariusz, Pobłocki, Kacper, Kowalczyk, Paweł, Kramkowski, Karol, Drzeżdżon, Joanna, Gawdzik, Barbara, Świtała, Patrycja, Miler, Maja, Heleniak, Daria, Rybiński, Przemysław, Jacewicz, Dagmara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9694032/
https://www.ncbi.nlm.nih.gov/pubmed/36432140
http://dx.doi.org/10.3390/molecules27228038
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author Urbaniak, Mariusz
Pobłocki, Kacper
Kowalczyk, Paweł
Kramkowski, Karol
Drzeżdżon, Joanna
Gawdzik, Barbara
Świtała, Patrycja
Miler, Maja
Heleniak, Daria
Rybiński, Przemysław
Jacewicz, Dagmara
author_facet Urbaniak, Mariusz
Pobłocki, Kacper
Kowalczyk, Paweł
Kramkowski, Karol
Drzeżdżon, Joanna
Gawdzik, Barbara
Świtała, Patrycja
Miler, Maja
Heleniak, Daria
Rybiński, Przemysław
Jacewicz, Dagmara
author_sort Urbaniak, Mariusz
collection PubMed
description Designing catalyst systems based on transition metal ions and activators using the principles of green chemistry is a fundamental research goal of scientists due to the reduction of poisonous solvents, metal salts and organic ligands released into the environment. Urgent measures to reduce climate change are in line with the goals of sustainable development and the new restrictive laws ordained by the European Union. In this report, we attempted to use known oxovanadium(IV) green complex compounds with O, N and S donor ligands, i.e., [VO(TDA)phen] • 1.5 H(2)O (TDA = thiodiacetate), (phen = 1,10-phenanthroline), oxovanadium(IV) microclusters with 2-phenylpyridine (oxovanadium(IV) cage), [VOO(dipic)(2-phepyH)] • H(2)O (dipic = pyridine-2,6-dicarboxylate anion), (2-phepyH = 2-phenylpyridine), [VO(dipic)(dmbipy)] • 2H(2)O (dmbipy = 4,4′-dimethoxy-2,2′-dipyridyl) and [VO(ODA)(bipy)] • 2 H(2)O (ODA = oxydiacetate), (bipy = 2,2′-bipyridine), as precatalysts in oligomerization reactions of 3-buten-2-ol, 2-propen-1-ol, 2-chloro-2-propen-1-ol and 2,3-dibromo-2-propen-1-ol. The precatalysts, in most cases, turned out to be highly active because the catalytic activity exceeded 1000 g mmol(−1)·h(−1). In addition, the oligomers were characterized by Fourier-transform infrared spectroscopy (FTIR), matrix-assisted laser desorption/ionization (MALDI-TOF-MS), thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) techniques.
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spelling pubmed-96940322022-11-26 A Series of Green Oxovanadium(IV) Precatalysts with O, N and S Donor Ligands in a Sustainable Olefins Oligomerization Process Urbaniak, Mariusz Pobłocki, Kacper Kowalczyk, Paweł Kramkowski, Karol Drzeżdżon, Joanna Gawdzik, Barbara Świtała, Patrycja Miler, Maja Heleniak, Daria Rybiński, Przemysław Jacewicz, Dagmara Molecules Article Designing catalyst systems based on transition metal ions and activators using the principles of green chemistry is a fundamental research goal of scientists due to the reduction of poisonous solvents, metal salts and organic ligands released into the environment. Urgent measures to reduce climate change are in line with the goals of sustainable development and the new restrictive laws ordained by the European Union. In this report, we attempted to use known oxovanadium(IV) green complex compounds with O, N and S donor ligands, i.e., [VO(TDA)phen] • 1.5 H(2)O (TDA = thiodiacetate), (phen = 1,10-phenanthroline), oxovanadium(IV) microclusters with 2-phenylpyridine (oxovanadium(IV) cage), [VOO(dipic)(2-phepyH)] • H(2)O (dipic = pyridine-2,6-dicarboxylate anion), (2-phepyH = 2-phenylpyridine), [VO(dipic)(dmbipy)] • 2H(2)O (dmbipy = 4,4′-dimethoxy-2,2′-dipyridyl) and [VO(ODA)(bipy)] • 2 H(2)O (ODA = oxydiacetate), (bipy = 2,2′-bipyridine), as precatalysts in oligomerization reactions of 3-buten-2-ol, 2-propen-1-ol, 2-chloro-2-propen-1-ol and 2,3-dibromo-2-propen-1-ol. The precatalysts, in most cases, turned out to be highly active because the catalytic activity exceeded 1000 g mmol(−1)·h(−1). In addition, the oligomers were characterized by Fourier-transform infrared spectroscopy (FTIR), matrix-assisted laser desorption/ionization (MALDI-TOF-MS), thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) techniques. MDPI 2022-11-19 /pmc/articles/PMC9694032/ /pubmed/36432140 http://dx.doi.org/10.3390/molecules27228038 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Urbaniak, Mariusz
Pobłocki, Kacper
Kowalczyk, Paweł
Kramkowski, Karol
Drzeżdżon, Joanna
Gawdzik, Barbara
Świtała, Patrycja
Miler, Maja
Heleniak, Daria
Rybiński, Przemysław
Jacewicz, Dagmara
A Series of Green Oxovanadium(IV) Precatalysts with O, N and S Donor Ligands in a Sustainable Olefins Oligomerization Process
title A Series of Green Oxovanadium(IV) Precatalysts with O, N and S Donor Ligands in a Sustainable Olefins Oligomerization Process
title_full A Series of Green Oxovanadium(IV) Precatalysts with O, N and S Donor Ligands in a Sustainable Olefins Oligomerization Process
title_fullStr A Series of Green Oxovanadium(IV) Precatalysts with O, N and S Donor Ligands in a Sustainable Olefins Oligomerization Process
title_full_unstemmed A Series of Green Oxovanadium(IV) Precatalysts with O, N and S Donor Ligands in a Sustainable Olefins Oligomerization Process
title_short A Series of Green Oxovanadium(IV) Precatalysts with O, N and S Donor Ligands in a Sustainable Olefins Oligomerization Process
title_sort series of green oxovanadium(iv) precatalysts with o, n and s donor ligands in a sustainable olefins oligomerization process
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9694032/
https://www.ncbi.nlm.nih.gov/pubmed/36432140
http://dx.doi.org/10.3390/molecules27228038
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