Magnetic Zinc Oxide/Manganese Ferrite Composite for Photodegradation of the Antibiotic Rifampicin

In this study, a composite of zinc oxide and manganese ferrite was synthesized using co-precipitation and hydrothermal routes, to be used as photocatalysts in reactions with UV/Vis light source. The synthesized materials were characterized by FTIR, XRD, and SEM, where it was possible to verify the efficiency of the syntheses performed, through the identification of the resulting phases, the evaluation of the structural morphology of the particles, and the analysis of the detachments of the main vibration bonds present in these materials. The composite ZnO/MnFe(2)O(4) was used in photodegradation reactions of the antibiotic rifampicin, with catalyst dosage of 0.20; 0.40, and 0.60 g and 10 ppm of rifampicin, reactions using pure ZnO as a catalyst were also performed as a comparative parameter of the influence of MnFe(2)O(4) in this system. The composite ZnO/MnFe(2)O(4) showed a maximum percentage of rifampicin decontamination of 94.72% and ZnO, 74.20%using 0.20 g of photocatalyst after 90 min, which indicates a positive influence on this process. The solution treated with ZnO/MnFe(2)O(4) was subjected to magnetic field induction for attraction and consequently accelerated removal of the solids present, successfully, compacting for the application of ZnO/MnFe(2)O(4) to be presented as a promising material for decontamination of emerging pollutants through photocatalytic reactions.