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Formal total synthesis of macarpine via a Au(I)-catalyzed 6-endo-dig cycloisomerization strategy
The formal total synthesis of macarpine was accomplished by the construction of a naphthol intermediate in Ishikawa’s synthetic route with two different synthetic routes. The convergent synthetic strategies feature the utilization of Au(I)-catalyzed cycloisomerizations of a 1,5-enyne and alkynyl ket...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9704023/ https://www.ncbi.nlm.nih.gov/pubmed/36483093 http://dx.doi.org/10.3762/bjoc.18.169 |