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Formal total synthesis of macarpine via a Au(I)-catalyzed 6-endo-dig cycloisomerization strategy

The formal total synthesis of macarpine was accomplished by the construction of a naphthol intermediate in Ishikawa’s synthetic route with two different synthetic routes. The convergent synthetic strategies feature the utilization of Au(I)-catalyzed cycloisomerizations of a 1,5-enyne and alkynyl ket...

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Detalles Bibliográficos
Autores principales:	Fu, Jiayue, Li, Bingbing, Zhou, Zefang, Cheng, Maosheng, Yang, Lu, Liu, Yongxiang
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2022
Materias:	Letter
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9704023/ https://www.ncbi.nlm.nih.gov/pubmed/36483093 http://dx.doi.org/10.3762/bjoc.18.169

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