Divergent Synthesis of Functionalized Indenopyridin-2-ones and 2-Pyridones via Benzyl Group Transfer: Two Cases of Aza-semipinacol-Type Rearrangement

[Image: see text] The synthesis of bromo-substituted indeno[1,2-b]pyridin-2-ones and 3-iodo-5-benzyl-substituted 2-pyridones, starting from easily available 6-benzyl-3,6-dihydropyridin-2(1H)-ones, triggered by NBS and NIS, respectively, is described. In both syntheses, a transfer of a benzyl group f...

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Detalles Bibliográficos
Autores principales: Sośnicki, Jacek G., Borzyszkowska-Ledwig, Aleksandra, Idzik, Tomasz J., Lubowicz, Magdalena M., Maciejewska, Gabriela, Struk, Łukasz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9706813/
https://www.ncbi.nlm.nih.gov/pubmed/36367325
http://dx.doi.org/10.1021/acs.orglett.2c03361

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9706813/
https://www.ncbi.nlm.nih.gov/pubmed/36367325
http://dx.doi.org/10.1021/acs.orglett.2c03361

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