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Single-Crystal to Single-Crystal Addition of H(2) to [Ir((i)Pr-PONOP)(propene)][BAr(F)(4)] and Comparison Between Solid-State and Solution Reactivity
[Image: see text] The reactivity of the Ir(I) PONOP pincer complex [Ir((i)Pr-PONOP)(η(2)-propene)][BAr(F)(4)], 6, [(i)Pr-PONOP = 2,6-((i)Pr(2)PO)(2)C(6)H(3)N, Ar(F) = 3,5-(CF(3))(2)C(6)H(3)] was studied in solution and the solid state, both experimentally, using molecular density functional theory (...
Autores principales: | Royle, Cameron G., Sotorrios, Lia, Gyton, Matthew R., Brodie, Claire N., Burnage, Arron L., Furfari, Samantha K., Marini, Anna, Warren, Mark R., Macgregor, Stuart A., Weller, Andrew S. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9709992/ https://www.ncbi.nlm.nih.gov/pubmed/36466791 http://dx.doi.org/10.1021/acs.organomet.2c00274 |
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