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Decarboxylative ring-opening of 2-oxazolidinones: a facile and modular synthesis of β-chalcogen amines
We report herein the synthesis of primary and secondary β-chalcogen amines through the regioselective ring-opening reaction of non-activated 2-oxazolidinones promoted by in situ generated chalcogenolate anions. The developed one-step protocol enabled the preparation of β-selenoamines, β-telluroamine...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9710311/ https://www.ncbi.nlm.nih.gov/pubmed/36545628 http://dx.doi.org/10.1039/d2ra06070a |
| _version_ | 1784841337464422400 |
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| author | Galetto, Fábio Z. da Silva, Cleiton Beche, Ricardo I. M. Balaguez, Renata A. Franco, Marcelo S. de Assis, Francisco F. Frizon, Tiago E. A. Su, Xiao |
| author_facet | Galetto, Fábio Z. da Silva, Cleiton Beche, Ricardo I. M. Balaguez, Renata A. Franco, Marcelo S. de Assis, Francisco F. Frizon, Tiago E. A. Su, Xiao |
| author_sort | Galetto, Fábio Z. |
| collection | PubMed |
| description | We report herein the synthesis of primary and secondary β-chalcogen amines through the regioselective ring-opening reaction of non-activated 2-oxazolidinones promoted by in situ generated chalcogenolate anions. The developed one-step protocol enabled the preparation of β-selenoamines, β-telluroamines and β-thioamines with appreciable structural diversity and in yields of up to 95%. |
| format | Online Article Text |
| id | pubmed-9710311 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2022 |
| publisher | The Royal Society of Chemistry |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-97103112022-12-20 Decarboxylative ring-opening of 2-oxazolidinones: a facile and modular synthesis of β-chalcogen amines Galetto, Fábio Z. da Silva, Cleiton Beche, Ricardo I. M. Balaguez, Renata A. Franco, Marcelo S. de Assis, Francisco F. Frizon, Tiago E. A. Su, Xiao RSC Adv Chemistry We report herein the synthesis of primary and secondary β-chalcogen amines through the regioselective ring-opening reaction of non-activated 2-oxazolidinones promoted by in situ generated chalcogenolate anions. The developed one-step protocol enabled the preparation of β-selenoamines, β-telluroamines and β-thioamines with appreciable structural diversity and in yields of up to 95%. The Royal Society of Chemistry 2022-11-30 /pmc/articles/PMC9710311/ /pubmed/36545628 http://dx.doi.org/10.1039/d2ra06070a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
| spellingShingle | Chemistry Galetto, Fábio Z. da Silva, Cleiton Beche, Ricardo I. M. Balaguez, Renata A. Franco, Marcelo S. de Assis, Francisco F. Frizon, Tiago E. A. Su, Xiao Decarboxylative ring-opening of 2-oxazolidinones: a facile and modular synthesis of β-chalcogen amines |
| title | Decarboxylative ring-opening of 2-oxazolidinones: a facile and modular synthesis of β-chalcogen amines |
| title_full | Decarboxylative ring-opening of 2-oxazolidinones: a facile and modular synthesis of β-chalcogen amines |
| title_fullStr | Decarboxylative ring-opening of 2-oxazolidinones: a facile and modular synthesis of β-chalcogen amines |
| title_full_unstemmed | Decarboxylative ring-opening of 2-oxazolidinones: a facile and modular synthesis of β-chalcogen amines |
| title_short | Decarboxylative ring-opening of 2-oxazolidinones: a facile and modular synthesis of β-chalcogen amines |
| title_sort | decarboxylative ring-opening of 2-oxazolidinones: a facile and modular synthesis of β-chalcogen amines |
| topic | Chemistry |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9710311/ https://www.ncbi.nlm.nih.gov/pubmed/36545628 http://dx.doi.org/10.1039/d2ra06070a |
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