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Azoarene activation for Schmidt-type reaction and mechanistic insights

The Schmidt rearrangement, a reaction that enables C-C or C-H σ bond cleavage and nitrogen insertion across an aldehyde or ketone substrate, is one of the most important and widely used synthetic tools for the installation of amides and nitriles. However, such a reaction frequently requires volatile...

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Detalles Bibliográficos
Autores principales:	Meng, Fan-Tao, Wang, Ya-Nan, Qin, Xiao-Yan, Li, Shi-Jun, Li, Jing, Hao, Wen-Juan, Tu, Shu-Jiang, Lan, Yu, Jiang, Bo
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9712421/ https://www.ncbi.nlm.nih.gov/pubmed/36450750 http://dx.doi.org/10.1038/s41467-022-35141-4

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