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Efficient Removal of Inorganic and Organic Pollutants over a NiCo(2)O(4)@MOF-801@MIL88A Photocatalyst: The Significance of Ternary Heterojunction Engineering

[Image: see text] Energy problems are a substantial concern in a global society that can be solved by replacing with sustainable energies. In recent years, designing nanomaterials as photocatalysts that can produce chemical energy with the utilization of infinite visible light energy became a new so...

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Autores principales: Bakhtian, Mahnaz, Khosroshahi, Negin, Safarifard, Vahid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9713798/
https://www.ncbi.nlm.nih.gov/pubmed/36467958
http://dx.doi.org/10.1021/acsomega.2c05000
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author Bakhtian, Mahnaz
Khosroshahi, Negin
Safarifard, Vahid
author_facet Bakhtian, Mahnaz
Khosroshahi, Negin
Safarifard, Vahid
author_sort Bakhtian, Mahnaz
collection PubMed
description [Image: see text] Energy problems are a substantial concern in a global society that can be solved by replacing with sustainable energies. In recent years, designing nanomaterials as photocatalysts that can produce chemical energy with the utilization of infinite visible light energy became a new solution for water treatment. In the present study, NiCo(2)O(4)@MOF-801 has been synthesized with multiple properties, and then, a novel three-layer NiCo(2)O(4)@MOF-801@MIL88A photocatalyst has been successfully synthesized to improve meropenem degradation and Cr(VI) reduction. The prepared photocatalyst was characterized by XRD, IR, XPS, TEM, SEM, TGA, BET, EIS, PL, and UV–vis. According to the structural and optical analysis performed, the interaction between the components formed a heterojunction structure that prevented the recombination of charge carriers and increased the photocatalytic performance. Photocatalytic simulation tests also proved the reduction of chromium and degradation of antibiotics to find the optimal heterogeneous performance. As a result, the NiCo(2)O(4)@MOF-801@MIL88A composite can completely reduce Cr(VI) in 45 min, which is strongly preferable to any pure component’s performance. Overall, this work offers a low-cost but high-efficiency material that can remove organic and inorganic contaminants from water.
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spelling pubmed-97137982022-12-02 Efficient Removal of Inorganic and Organic Pollutants over a NiCo(2)O(4)@MOF-801@MIL88A Photocatalyst: The Significance of Ternary Heterojunction Engineering Bakhtian, Mahnaz Khosroshahi, Negin Safarifard, Vahid ACS Omega [Image: see text] Energy problems are a substantial concern in a global society that can be solved by replacing with sustainable energies. In recent years, designing nanomaterials as photocatalysts that can produce chemical energy with the utilization of infinite visible light energy became a new solution for water treatment. In the present study, NiCo(2)O(4)@MOF-801 has been synthesized with multiple properties, and then, a novel three-layer NiCo(2)O(4)@MOF-801@MIL88A photocatalyst has been successfully synthesized to improve meropenem degradation and Cr(VI) reduction. The prepared photocatalyst was characterized by XRD, IR, XPS, TEM, SEM, TGA, BET, EIS, PL, and UV–vis. According to the structural and optical analysis performed, the interaction between the components formed a heterojunction structure that prevented the recombination of charge carriers and increased the photocatalytic performance. Photocatalytic simulation tests also proved the reduction of chromium and degradation of antibiotics to find the optimal heterogeneous performance. As a result, the NiCo(2)O(4)@MOF-801@MIL88A composite can completely reduce Cr(VI) in 45 min, which is strongly preferable to any pure component’s performance. Overall, this work offers a low-cost but high-efficiency material that can remove organic and inorganic contaminants from water. American Chemical Society 2022-11-15 /pmc/articles/PMC9713798/ /pubmed/36467958 http://dx.doi.org/10.1021/acsomega.2c05000 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Bakhtian, Mahnaz
Khosroshahi, Negin
Safarifard, Vahid
Efficient Removal of Inorganic and Organic Pollutants over a NiCo(2)O(4)@MOF-801@MIL88A Photocatalyst: The Significance of Ternary Heterojunction Engineering
title Efficient Removal of Inorganic and Organic Pollutants over a NiCo(2)O(4)@MOF-801@MIL88A Photocatalyst: The Significance of Ternary Heterojunction Engineering
title_full Efficient Removal of Inorganic and Organic Pollutants over a NiCo(2)O(4)@MOF-801@MIL88A Photocatalyst: The Significance of Ternary Heterojunction Engineering
title_fullStr Efficient Removal of Inorganic and Organic Pollutants over a NiCo(2)O(4)@MOF-801@MIL88A Photocatalyst: The Significance of Ternary Heterojunction Engineering
title_full_unstemmed Efficient Removal of Inorganic and Organic Pollutants over a NiCo(2)O(4)@MOF-801@MIL88A Photocatalyst: The Significance of Ternary Heterojunction Engineering
title_short Efficient Removal of Inorganic and Organic Pollutants over a NiCo(2)O(4)@MOF-801@MIL88A Photocatalyst: The Significance of Ternary Heterojunction Engineering
title_sort efficient removal of inorganic and organic pollutants over a nico(2)o(4)@mof-801@mil88a photocatalyst: the significance of ternary heterojunction engineering
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9713798/
https://www.ncbi.nlm.nih.gov/pubmed/36467958
http://dx.doi.org/10.1021/acsomega.2c05000
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