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Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt
A glassy carbon electrode (GCE) has been modified by an in situ electrochemical reduction of an aryldiazonium salt generated from the reaction of 4‐aminobenzoic acid and sodium nitrite in acidic ethanolic solution. The as‐prepared phenyl carboxylic acid‐modified glassy carbon electrode has been, for...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9728485/ https://www.ncbi.nlm.nih.gov/pubmed/36478448 http://dx.doi.org/10.1002/open.202200233 |
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author | Anjum, Saima Lou, Baohua Tahir, Amiza Aziz‐ur‐Rehman, Rehan H. Shah Gilani, M. Xu, Guobao |
author_facet | Anjum, Saima Lou, Baohua Tahir, Amiza Aziz‐ur‐Rehman, Rehan H. Shah Gilani, M. Xu, Guobao |
author_sort | Anjum, Saima |
collection | PubMed |
description | A glassy carbon electrode (GCE) has been modified by an in situ electrochemical reduction of an aryldiazonium salt generated from the reaction of 4‐aminobenzoic acid and sodium nitrite in acidic ethanolic solution. The as‐prepared phenyl carboxylic acid‐modified glassy carbon electrode has been, for the first time, used for the electrochemical determination of dopamine. Under optimal experimental parameters, outstanding electrocatalytic activity, high sensitivity at a LOD of 5.6×10(−9) m, and broad linearity of 0.1 to 1000 μm were obtained. The crafted electrochemical platform demonstrated excellent stability, specificity, and anti‐interference capability towards the sensing of dopamine. |
format | Online Article Text |
id | pubmed-9728485 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-97284852022-12-08 Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt Anjum, Saima Lou, Baohua Tahir, Amiza Aziz‐ur‐Rehman, Rehan H. Shah Gilani, M. Xu, Guobao ChemistryOpen Research Articles A glassy carbon electrode (GCE) has been modified by an in situ electrochemical reduction of an aryldiazonium salt generated from the reaction of 4‐aminobenzoic acid and sodium nitrite in acidic ethanolic solution. The as‐prepared phenyl carboxylic acid‐modified glassy carbon electrode has been, for the first time, used for the electrochemical determination of dopamine. Under optimal experimental parameters, outstanding electrocatalytic activity, high sensitivity at a LOD of 5.6×10(−9) m, and broad linearity of 0.1 to 1000 μm were obtained. The crafted electrochemical platform demonstrated excellent stability, specificity, and anti‐interference capability towards the sensing of dopamine. John Wiley and Sons Inc. 2022-12-07 /pmc/articles/PMC9728485/ /pubmed/36478448 http://dx.doi.org/10.1002/open.202200233 Text en © 2022 The Authors. Published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Research Articles Anjum, Saima Lou, Baohua Tahir, Amiza Aziz‐ur‐Rehman, Rehan H. Shah Gilani, M. Xu, Guobao Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt |
title | Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt |
title_full | Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt |
title_fullStr | Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt |
title_full_unstemmed | Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt |
title_short | Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt |
title_sort | electrochemical detection of dopamine using a phenyl carboxylic acid‐functionalized electrode made by electrochemical reduction of a diazonium salt |
topic | Research Articles |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9728485/ https://www.ncbi.nlm.nih.gov/pubmed/36478448 http://dx.doi.org/10.1002/open.202200233 |
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