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Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt

A glassy carbon electrode (GCE) has been modified by an in situ electrochemical reduction of an aryldiazonium salt generated from the reaction of 4‐aminobenzoic acid and sodium nitrite in acidic ethanolic solution. The as‐prepared phenyl carboxylic acid‐modified glassy carbon electrode has been, for...

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Autores principales: Anjum, Saima, Lou, Baohua, Tahir, Amiza, Aziz‐ur‐Rehman, Rehan H. Shah Gilani, M., Xu, Guobao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9728485/
https://www.ncbi.nlm.nih.gov/pubmed/36478448
http://dx.doi.org/10.1002/open.202200233
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author Anjum, Saima
Lou, Baohua
Tahir, Amiza
Aziz‐ur‐Rehman,
Rehan H. Shah Gilani, M.
Xu, Guobao
author_facet Anjum, Saima
Lou, Baohua
Tahir, Amiza
Aziz‐ur‐Rehman,
Rehan H. Shah Gilani, M.
Xu, Guobao
author_sort Anjum, Saima
collection PubMed
description A glassy carbon electrode (GCE) has been modified by an in situ electrochemical reduction of an aryldiazonium salt generated from the reaction of 4‐aminobenzoic acid and sodium nitrite in acidic ethanolic solution. The as‐prepared phenyl carboxylic acid‐modified glassy carbon electrode has been, for the first time, used for the electrochemical determination of dopamine. Under optimal experimental parameters, outstanding electrocatalytic activity, high sensitivity at a LOD of 5.6×10(−9)  m, and broad linearity of 0.1 to 1000 μm were obtained. The crafted electrochemical platform demonstrated excellent stability, specificity, and anti‐interference capability towards the sensing of dopamine.
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spelling pubmed-97284852022-12-08 Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt Anjum, Saima Lou, Baohua Tahir, Amiza Aziz‐ur‐Rehman, Rehan H. Shah Gilani, M. Xu, Guobao ChemistryOpen Research Articles A glassy carbon electrode (GCE) has been modified by an in situ electrochemical reduction of an aryldiazonium salt generated from the reaction of 4‐aminobenzoic acid and sodium nitrite in acidic ethanolic solution. The as‐prepared phenyl carboxylic acid‐modified glassy carbon electrode has been, for the first time, used for the electrochemical determination of dopamine. Under optimal experimental parameters, outstanding electrocatalytic activity, high sensitivity at a LOD of 5.6×10(−9)  m, and broad linearity of 0.1 to 1000 μm were obtained. The crafted electrochemical platform demonstrated excellent stability, specificity, and anti‐interference capability towards the sensing of dopamine. John Wiley and Sons Inc. 2022-12-07 /pmc/articles/PMC9728485/ /pubmed/36478448 http://dx.doi.org/10.1002/open.202200233 Text en © 2022 The Authors. Published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Articles
Anjum, Saima
Lou, Baohua
Tahir, Amiza
Aziz‐ur‐Rehman,
Rehan H. Shah Gilani, M.
Xu, Guobao
Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt
title Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt
title_full Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt
title_fullStr Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt
title_full_unstemmed Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt
title_short Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt
title_sort electrochemical detection of dopamine using a phenyl carboxylic acid‐functionalized electrode made by electrochemical reduction of a diazonium salt
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9728485/
https://www.ncbi.nlm.nih.gov/pubmed/36478448
http://dx.doi.org/10.1002/open.202200233
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