Backbone-controlled LUMO energy induces intramolecular C–H activation in ortho-bis-9-borafluorene-substituted phenyl and o-carboranyl compounds leading to novel 9,10-diboraanthracene derivatives

The choice of backbone linker for two ortho-bis-(9-borafluorene)s has a great influence on the LUMO located at the boron centers and, therefore, the reactivity of the respective compounds. Herein, we report the room temperature rearrangement of 1,2-bis-(9-borafluorenyl)-ortho-carborane, C(2)B(10)H(1...

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Detalles Bibliográficos
Autores principales: Krebs, Johannes, Häfner, Alena, Fuchs, Sonja, Guo, Xueying, Rauch, Florian, Eichhorn, Antonius, Krummenacher, Ivo, Friedrich, Alexandra, Ji, Lei, Finze, Maik, Lin, Zhenyang, Braunschweig, Holger, Marder, Todd B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9728567/
https://www.ncbi.nlm.nih.gov/pubmed/36540825
http://dx.doi.org/10.1039/d2sc06057d

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