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Mixed chloridometallate(ii) ionic liquids with tunable color and optical response for potential ammonia sensors
Eight d-metal-containing N-butylpyridinium ionic liquids (ILs) with the nominal composition (C(4)Py)(2)[Ni(0.5)M(0.5)Cl(4)] or (C(4)Py)(2)[Zn(0.5)M(0.5)Cl(4)] (M = Cu, Co, Mn, Ni, Zn; C(4)Py = N-butylpyridinium) were synthesized, characterized, and investigated for their optical properties. Single c...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9729802/ https://www.ncbi.nlm.nih.gov/pubmed/36540267 http://dx.doi.org/10.1039/d2ra05581c |
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author | Behrens, Karsten Balischewski, Christian Sperlich, Eric Menski, Antonia Balderas-Valadez, Ruth Fabiola Pacholski, Claudia Günter, Christina Lubahn, Susanne Kelling, Alexandra Taubert, Andreas |
author_facet | Behrens, Karsten Balischewski, Christian Sperlich, Eric Menski, Antonia Balderas-Valadez, Ruth Fabiola Pacholski, Claudia Günter, Christina Lubahn, Susanne Kelling, Alexandra Taubert, Andreas |
author_sort | Behrens, Karsten |
collection | PubMed |
description | Eight d-metal-containing N-butylpyridinium ionic liquids (ILs) with the nominal composition (C(4)Py)(2)[Ni(0.5)M(0.5)Cl(4)] or (C(4)Py)(2)[Zn(0.5)M(0.5)Cl(4)] (M = Cu, Co, Mn, Ni, Zn; C(4)Py = N-butylpyridinium) were synthesized, characterized, and investigated for their optical properties. Single crystal and powder X-ray analysis shows that the compounds are isostructural to existing examples based on other d-metal ions. Inductively coupled plasma optical emission spectroscopy measurements confirm that the metal/metal ratio is around 50 : 50. UV-Vis spectroscopy shows that the optical absorption can be tuned by selection of the constituent metals. Moreover, the compounds can act as an optical sensor for the detection of gases such as ammonia as demonstrated via a simple prototype setup. |
format | Online Article Text |
id | pubmed-9729802 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-97298022022-12-19 Mixed chloridometallate(ii) ionic liquids with tunable color and optical response for potential ammonia sensors Behrens, Karsten Balischewski, Christian Sperlich, Eric Menski, Antonia Balderas-Valadez, Ruth Fabiola Pacholski, Claudia Günter, Christina Lubahn, Susanne Kelling, Alexandra Taubert, Andreas RSC Adv Chemistry Eight d-metal-containing N-butylpyridinium ionic liquids (ILs) with the nominal composition (C(4)Py)(2)[Ni(0.5)M(0.5)Cl(4)] or (C(4)Py)(2)[Zn(0.5)M(0.5)Cl(4)] (M = Cu, Co, Mn, Ni, Zn; C(4)Py = N-butylpyridinium) were synthesized, characterized, and investigated for their optical properties. Single crystal and powder X-ray analysis shows that the compounds are isostructural to existing examples based on other d-metal ions. Inductively coupled plasma optical emission spectroscopy measurements confirm that the metal/metal ratio is around 50 : 50. UV-Vis spectroscopy shows that the optical absorption can be tuned by selection of the constituent metals. Moreover, the compounds can act as an optical sensor for the detection of gases such as ammonia as demonstrated via a simple prototype setup. The Royal Society of Chemistry 2022-12-08 /pmc/articles/PMC9729802/ /pubmed/36540267 http://dx.doi.org/10.1039/d2ra05581c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Behrens, Karsten Balischewski, Christian Sperlich, Eric Menski, Antonia Balderas-Valadez, Ruth Fabiola Pacholski, Claudia Günter, Christina Lubahn, Susanne Kelling, Alexandra Taubert, Andreas Mixed chloridometallate(ii) ionic liquids with tunable color and optical response for potential ammonia sensors |
title | Mixed chloridometallate(ii) ionic liquids with tunable color and optical response for potential ammonia sensors |
title_full | Mixed chloridometallate(ii) ionic liquids with tunable color and optical response for potential ammonia sensors |
title_fullStr | Mixed chloridometallate(ii) ionic liquids with tunable color and optical response for potential ammonia sensors |
title_full_unstemmed | Mixed chloridometallate(ii) ionic liquids with tunable color and optical response for potential ammonia sensors |
title_short | Mixed chloridometallate(ii) ionic liquids with tunable color and optical response for potential ammonia sensors |
title_sort | mixed chloridometallate(ii) ionic liquids with tunable color and optical response for potential ammonia sensors |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9729802/ https://www.ncbi.nlm.nih.gov/pubmed/36540267 http://dx.doi.org/10.1039/d2ra05581c |
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