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Self-assembled wide bandgap nanocoatings enabled outstanding dielectric characteristics in the sandwich-like structure polymer composites

Polymer dielectrics are insulators or energy storage materials widely used in electrical and electronic devices. Polymer dielectrics are needed with outstanding dielectric characteristics than current technologies. In this study, the self-assembly of boron nitride nanosheets (BNNSs) was applied to f...

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Autores principales: Wang, Tian-Yu, Li, Xiao-Fen, Liu, Shu-Ming, Liu, Bai-Xin, Liang, Xi-Dong, Li, Shunning, Zhang, Gui-Xin, Liu, Jian-Bo, Dang, Zhi-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Nature Singapore 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9733754/
https://www.ncbi.nlm.nih.gov/pubmed/36484882
http://dx.doi.org/10.1186/s40580-022-00346-2
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author Wang, Tian-Yu
Li, Xiao-Fen
Liu, Shu-Ming
Liu, Bai-Xin
Liang, Xi-Dong
Li, Shunning
Zhang, Gui-Xin
Liu, Jian-Bo
Dang, Zhi-Min
author_facet Wang, Tian-Yu
Li, Xiao-Fen
Liu, Shu-Ming
Liu, Bai-Xin
Liang, Xi-Dong
Li, Shunning
Zhang, Gui-Xin
Liu, Jian-Bo
Dang, Zhi-Min
author_sort Wang, Tian-Yu
collection PubMed
description Polymer dielectrics are insulators or energy storage materials widely used in electrical and electronic devices. Polymer dielectrics are needed with outstanding dielectric characteristics than current technologies. In this study, the self-assembly of boron nitride nanosheets (BNNSs) was applied to form an inorganic–organic nanocoating on various common polymer dielectrics. It is inexpensive and easy to fabricate this thin coating on a large scale. The coating has a wide bandgap and thus can significantly improve the breakdown strength of polymer dielectrics. The charge characteristics and trapping parameters of nano-domains on the surfaces of polymer dielectrics were measured, and the coating had shallow trap levels. This facilitated the dissipation of surface charges and thus greatly increased the flashover voltage. The coating also effectively improved the temperature stability and dielectric constant of the polymer dielectric. This nanocoating shows potential as a method to effectively improve the dielectric characteristics of polymer dielectrics and outperform existing composite polymer dielectrics, which are crucial for large-scale applications in energy storage and power and electronic devices. SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1186/s40580-022-00346-2.
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spelling pubmed-97337542022-12-10 Self-assembled wide bandgap nanocoatings enabled outstanding dielectric characteristics in the sandwich-like structure polymer composites Wang, Tian-Yu Li, Xiao-Fen Liu, Shu-Ming Liu, Bai-Xin Liang, Xi-Dong Li, Shunning Zhang, Gui-Xin Liu, Jian-Bo Dang, Zhi-Min Nano Converg Full Paper Polymer dielectrics are insulators or energy storage materials widely used in electrical and electronic devices. Polymer dielectrics are needed with outstanding dielectric characteristics than current technologies. In this study, the self-assembly of boron nitride nanosheets (BNNSs) was applied to form an inorganic–organic nanocoating on various common polymer dielectrics. It is inexpensive and easy to fabricate this thin coating on a large scale. The coating has a wide bandgap and thus can significantly improve the breakdown strength of polymer dielectrics. The charge characteristics and trapping parameters of nano-domains on the surfaces of polymer dielectrics were measured, and the coating had shallow trap levels. This facilitated the dissipation of surface charges and thus greatly increased the flashover voltage. The coating also effectively improved the temperature stability and dielectric constant of the polymer dielectric. This nanocoating shows potential as a method to effectively improve the dielectric characteristics of polymer dielectrics and outperform existing composite polymer dielectrics, which are crucial for large-scale applications in energy storage and power and electronic devices. SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1186/s40580-022-00346-2. Springer Nature Singapore 2022-12-09 /pmc/articles/PMC9733754/ /pubmed/36484882 http://dx.doi.org/10.1186/s40580-022-00346-2 Text en © The Author(s) 2022 https://creativecommons.org/licenses/by/4.0/Open AccessThis article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Full Paper
Wang, Tian-Yu
Li, Xiao-Fen
Liu, Shu-Ming
Liu, Bai-Xin
Liang, Xi-Dong
Li, Shunning
Zhang, Gui-Xin
Liu, Jian-Bo
Dang, Zhi-Min
Self-assembled wide bandgap nanocoatings enabled outstanding dielectric characteristics in the sandwich-like structure polymer composites
title Self-assembled wide bandgap nanocoatings enabled outstanding dielectric characteristics in the sandwich-like structure polymer composites
title_full Self-assembled wide bandgap nanocoatings enabled outstanding dielectric characteristics in the sandwich-like structure polymer composites
title_fullStr Self-assembled wide bandgap nanocoatings enabled outstanding dielectric characteristics in the sandwich-like structure polymer composites
title_full_unstemmed Self-assembled wide bandgap nanocoatings enabled outstanding dielectric characteristics in the sandwich-like structure polymer composites
title_short Self-assembled wide bandgap nanocoatings enabled outstanding dielectric characteristics in the sandwich-like structure polymer composites
title_sort self-assembled wide bandgap nanocoatings enabled outstanding dielectric characteristics in the sandwich-like structure polymer composites
topic Full Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9733754/
https://www.ncbi.nlm.nih.gov/pubmed/36484882
http://dx.doi.org/10.1186/s40580-022-00346-2
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