One-Dimensional Iodoantimonate(III) and Iodobismuthate(III) Supramolecular Hybrids with Diiodine: Structural Features, Stability and Optical Properties

Two isostructural pairs of supramolecular iodoantimonate(III) and iodobismuthate(III) complexes with I(2) units “trapped” in solid state via halogen bonding—Cat(3)[[M(2)I(9)](I(2))} (Cat = tetramethylammonium and 1-methylpyridinium, M = Sb(III) and Bi(III)) were prepared. For all compounds, values o...

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Autores principales: Korobeynikov, Nikita A., Usoltsev, Andrey N., Abramov, Pavel A., Sokolov, Maxim N., Adonin, Sergey A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9735928/
https://www.ncbi.nlm.nih.gov/pubmed/36500578
http://dx.doi.org/10.3390/molecules27238487
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author Korobeynikov, Nikita A.
Usoltsev, Andrey N.
Abramov, Pavel A.
Sokolov, Maxim N.
Adonin, Sergey A.
author_facet Korobeynikov, Nikita A.
Usoltsev, Andrey N.
Abramov, Pavel A.
Sokolov, Maxim N.
Adonin, Sergey A.
author_sort Korobeynikov, Nikita A.
collection PubMed
description Two isostructural pairs of supramolecular iodoantimonate(III) and iodobismuthate(III) complexes with I(2) units “trapped” in solid state via halogen bonding—Cat(3)[[M(2)I(9)](I(2))} (Cat = tetramethylammonium and 1-methylpyridinium, M = Sb(III) and Bi(III)) were prepared. For all compounds, values of optical band gaps were determined, together with thermal stability; the complexes were additionally characterized by Raman spectroscopy.
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spelling pubmed-97359282022-12-11 One-Dimensional Iodoantimonate(III) and Iodobismuthate(III) Supramolecular Hybrids with Diiodine: Structural Features, Stability and Optical Properties Korobeynikov, Nikita A. Usoltsev, Andrey N. Abramov, Pavel A. Sokolov, Maxim N. Adonin, Sergey A. Molecules Article Two isostructural pairs of supramolecular iodoantimonate(III) and iodobismuthate(III) complexes with I(2) units “trapped” in solid state via halogen bonding—Cat(3)[[M(2)I(9)](I(2))} (Cat = tetramethylammonium and 1-methylpyridinium, M = Sb(III) and Bi(III)) were prepared. For all compounds, values of optical band gaps were determined, together with thermal stability; the complexes were additionally characterized by Raman spectroscopy. MDPI 2022-12-02 /pmc/articles/PMC9735928/ /pubmed/36500578 http://dx.doi.org/10.3390/molecules27238487 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Korobeynikov, Nikita A.
Usoltsev, Andrey N.
Abramov, Pavel A.
Sokolov, Maxim N.
Adonin, Sergey A.
One-Dimensional Iodoantimonate(III) and Iodobismuthate(III) Supramolecular Hybrids with Diiodine: Structural Features, Stability and Optical Properties
title One-Dimensional Iodoantimonate(III) and Iodobismuthate(III) Supramolecular Hybrids with Diiodine: Structural Features, Stability and Optical Properties
title_full One-Dimensional Iodoantimonate(III) and Iodobismuthate(III) Supramolecular Hybrids with Diiodine: Structural Features, Stability and Optical Properties
title_fullStr One-Dimensional Iodoantimonate(III) and Iodobismuthate(III) Supramolecular Hybrids with Diiodine: Structural Features, Stability and Optical Properties
title_full_unstemmed One-Dimensional Iodoantimonate(III) and Iodobismuthate(III) Supramolecular Hybrids with Diiodine: Structural Features, Stability and Optical Properties
title_short One-Dimensional Iodoantimonate(III) and Iodobismuthate(III) Supramolecular Hybrids with Diiodine: Structural Features, Stability and Optical Properties
title_sort one-dimensional iodoantimonate(iii) and iodobismuthate(iii) supramolecular hybrids with diiodine: structural features, stability and optical properties
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9735928/
https://www.ncbi.nlm.nih.gov/pubmed/36500578
http://dx.doi.org/10.3390/molecules27238487
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