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Synthesis, Photochromic and Luminescent Properties of Ammonium Salts of Spiropyrans

New salts of photochromic indoline spiropyrans capable of reversibly responding to UV radiation were synthesized to develop light-controlled materials. Photoinduced reactions of the synthesized compounds were studied using absorption and luminescence spectroscopies, and the quantum yields of photois...

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Detalles Bibliográficos
Autores principales: Khuzin, Artur A., Galimov, Dim I., Tulyabaev, Artur R., Khuzina, Liliya L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9736937/
https://www.ncbi.nlm.nih.gov/pubmed/36500585
http://dx.doi.org/10.3390/molecules27238492
Descripción
Sumario:New salts of photochromic indoline spiropyrans capable of reversibly responding to UV radiation were synthesized to develop light-controlled materials. Photoinduced reactions of the synthesized compounds were studied using absorption and luminescence spectroscopies, and the quantum yields of photoisomerization and other spectral and kinetic characteristics were measured. It was shown that the light sensitivity and photostability of the synthesized compounds are considerably influenced by the length of the spacer between the indole and ammonium nitrogen atoms.