Synthesis and the Crystal Structure of a New Chiral 1D Metal–Organic Coordination Polymer Based on L-Prolineamide-Substituted Diarylacetylenedicarboxylic Acid Derivative

The new homochiral 1D metal–organic coordination polymer [Cu(2)(EDPB)•H(2)O](n) was synthesized starting from the original 3,3′-ethyne-1,2-diylbis[6-(L-prolylamino)benzoic acid] (H(4)EDPB). The unique crystal structure of the new compound was established by powder X-ray diffraction. The [Cu(2)(EDPB)...

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Autores principales: Veselovsky, Vladimir V., Isaeva, Vera I., Nissenbaum, Vera D., Kustov, Leonid M., Chernyshev, Vladimir V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9738848/
https://www.ncbi.nlm.nih.gov/pubmed/36500469
http://dx.doi.org/10.3390/molecules27238376
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author Veselovsky, Vladimir V.
Isaeva, Vera I.
Nissenbaum, Vera D.
Kustov, Leonid M.
Chernyshev, Vladimir V.
author_facet Veselovsky, Vladimir V.
Isaeva, Vera I.
Nissenbaum, Vera D.
Kustov, Leonid M.
Chernyshev, Vladimir V.
author_sort Veselovsky, Vladimir V.
collection PubMed
description The new homochiral 1D metal–organic coordination polymer [Cu(2)(EDPB)•H(2)O](n) was synthesized starting from the original 3,3′-ethyne-1,2-diylbis[6-(L-prolylamino)benzoic acid] (H(4)EDPB). The unique crystal structure of the new compound was established by powder X-ray diffraction. The [Cu(2)(EDPB)•H(2)O](n) system shows catalytic activity and enantioselectivity in a Henry reaction of p-nitrobenzaldehyde with nitromethane.
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spelling pubmed-97388482022-12-11 Synthesis and the Crystal Structure of a New Chiral 1D Metal–Organic Coordination Polymer Based on L-Prolineamide-Substituted Diarylacetylenedicarboxylic Acid Derivative Veselovsky, Vladimir V. Isaeva, Vera I. Nissenbaum, Vera D. Kustov, Leonid M. Chernyshev, Vladimir V. Molecules Article The new homochiral 1D metal–organic coordination polymer [Cu(2)(EDPB)•H(2)O](n) was synthesized starting from the original 3,3′-ethyne-1,2-diylbis[6-(L-prolylamino)benzoic acid] (H(4)EDPB). The unique crystal structure of the new compound was established by powder X-ray diffraction. The [Cu(2)(EDPB)•H(2)O](n) system shows catalytic activity and enantioselectivity in a Henry reaction of p-nitrobenzaldehyde with nitromethane. MDPI 2022-11-30 /pmc/articles/PMC9738848/ /pubmed/36500469 http://dx.doi.org/10.3390/molecules27238376 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Veselovsky, Vladimir V.
Isaeva, Vera I.
Nissenbaum, Vera D.
Kustov, Leonid M.
Chernyshev, Vladimir V.
Synthesis and the Crystal Structure of a New Chiral 1D Metal–Organic Coordination Polymer Based on L-Prolineamide-Substituted Diarylacetylenedicarboxylic Acid Derivative
title Synthesis and the Crystal Structure of a New Chiral 1D Metal–Organic Coordination Polymer Based on L-Prolineamide-Substituted Diarylacetylenedicarboxylic Acid Derivative
title_full Synthesis and the Crystal Structure of a New Chiral 1D Metal–Organic Coordination Polymer Based on L-Prolineamide-Substituted Diarylacetylenedicarboxylic Acid Derivative
title_fullStr Synthesis and the Crystal Structure of a New Chiral 1D Metal–Organic Coordination Polymer Based on L-Prolineamide-Substituted Diarylacetylenedicarboxylic Acid Derivative
title_full_unstemmed Synthesis and the Crystal Structure of a New Chiral 1D Metal–Organic Coordination Polymer Based on L-Prolineamide-Substituted Diarylacetylenedicarboxylic Acid Derivative
title_short Synthesis and the Crystal Structure of a New Chiral 1D Metal–Organic Coordination Polymer Based on L-Prolineamide-Substituted Diarylacetylenedicarboxylic Acid Derivative
title_sort synthesis and the crystal structure of a new chiral 1d metal–organic coordination polymer based on l-prolineamide-substituted diarylacetylenedicarboxylic acid derivative
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9738848/
https://www.ncbi.nlm.nih.gov/pubmed/36500469
http://dx.doi.org/10.3390/molecules27238376
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