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Hyperbranched Polyester Polyfumaratomaleate Doped with Gd(III) and Dy(III) Ions: Synthesis, Structure and Properties
For the first time, metal–polymer complexes have been synthesized using hyperbranched polyester polyfumaratomaleate as a matrix, the structure of which has been established by (1)H NMR, IR, electron spectroscopy, and elemental analysis methods. The formation of complexes with Gd(III) and Dy(III) ion...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9739669/ https://www.ncbi.nlm.nih.gov/pubmed/36501693 http://dx.doi.org/10.3390/polym14235298 |
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author | Maksimov, Aleksei Vagapova, Alina Kutyreva, Marianna Kutyrev, Gennadii |
author_facet | Maksimov, Aleksei Vagapova, Alina Kutyreva, Marianna Kutyrev, Gennadii |
author_sort | Maksimov, Aleksei |
collection | PubMed |
description | For the first time, metal–polymer complexes have been synthesized using hyperbranched polyester polyfumaratomaleate as a matrix, the structure of which has been established by (1)H NMR, IR, electron spectroscopy, and elemental analysis methods. The formation of complexes with Gd(III) and Dy(III) ions involving fumarate and maleate groups of the polyester was proved by IR and electron spectroscopy methods. It was established that the structure of the coordination units has the form of a square antiprism. The compositions and conditional logarithms of the stability constants of the complexes were determined. It was established that complexation with lanthanide ions promotes emission enhancement in the ligand. |
format | Online Article Text |
id | pubmed-9739669 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-97396692022-12-11 Hyperbranched Polyester Polyfumaratomaleate Doped with Gd(III) and Dy(III) Ions: Synthesis, Structure and Properties Maksimov, Aleksei Vagapova, Alina Kutyreva, Marianna Kutyrev, Gennadii Polymers (Basel) Article For the first time, metal–polymer complexes have been synthesized using hyperbranched polyester polyfumaratomaleate as a matrix, the structure of which has been established by (1)H NMR, IR, electron spectroscopy, and elemental analysis methods. The formation of complexes with Gd(III) and Dy(III) ions involving fumarate and maleate groups of the polyester was proved by IR and electron spectroscopy methods. It was established that the structure of the coordination units has the form of a square antiprism. The compositions and conditional logarithms of the stability constants of the complexes were determined. It was established that complexation with lanthanide ions promotes emission enhancement in the ligand. MDPI 2022-12-04 /pmc/articles/PMC9739669/ /pubmed/36501693 http://dx.doi.org/10.3390/polym14235298 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Maksimov, Aleksei Vagapova, Alina Kutyreva, Marianna Kutyrev, Gennadii Hyperbranched Polyester Polyfumaratomaleate Doped with Gd(III) and Dy(III) Ions: Synthesis, Structure and Properties |
title | Hyperbranched Polyester Polyfumaratomaleate Doped with Gd(III) and Dy(III) Ions: Synthesis, Structure and Properties |
title_full | Hyperbranched Polyester Polyfumaratomaleate Doped with Gd(III) and Dy(III) Ions: Synthesis, Structure and Properties |
title_fullStr | Hyperbranched Polyester Polyfumaratomaleate Doped with Gd(III) and Dy(III) Ions: Synthesis, Structure and Properties |
title_full_unstemmed | Hyperbranched Polyester Polyfumaratomaleate Doped with Gd(III) and Dy(III) Ions: Synthesis, Structure and Properties |
title_short | Hyperbranched Polyester Polyfumaratomaleate Doped with Gd(III) and Dy(III) Ions: Synthesis, Structure and Properties |
title_sort | hyperbranched polyester polyfumaratomaleate doped with gd(iii) and dy(iii) ions: synthesis, structure and properties |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9739669/ https://www.ncbi.nlm.nih.gov/pubmed/36501693 http://dx.doi.org/10.3390/polym14235298 |
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