Facile Synthesis of Two Dimensional (2D) V(2)O(5) Nanosheets Film towards Photodetectors

Most of the studies focused on V(2)O(5) have been devoted to obtaining specific morphology and microstructure for its intended applications. Two dimensional (2D) V(2)O(5) has the most valuable structure because of its unique planar configuration that can offer more active sites. In this study, a bottom-up and low-cost method that is hydrothermal combined with spin-coating and subsequent annealing was developed to prepare 2D V(2)O(5) nanosheets film on quartz substrate. First, VOOH nanosheets were prepared by the hydrothermal method using V(2)O(5) powders and EG as raw materials. Further, V(2)O(5) nanosheets with an average lateral size over 500 nm and thickness less than 10 nm can be prepared from the parent VOOH nanosheets by annealing at 350 °C for 15 min in air. The prepared V(2)O(5) nanosheets film was assembled of multiple nanosheets. The structural, morphological, microstructural and optical properties of the films were respective investigated by XRD, SEM, TEM and UV-Vis. The photodetector based on V(2)O(5) nanosheets film shows good photoresponse with a response time of 2.4 s and a recovery time of 4.7 s.