Organic–Inorganic Lead Halide Perovskite Single Crystal: From Synthesis to Applications

Organic–inorganic lead halide perovskite is widely used in the photoelectric field due to its excellent photoelectric characteristics. Among them, perovskite single crystals have attracted much attention due to its lower trap density and better carrier transport capacity than their corresponding polycrystalline materials. Owing to these characteristics, perovskite single crystals have been widely used in solar cells, photodetectors, light-emitting diode (LED), and so on, which have greater potential than polycrystals in a series of optoelectronic applications. However, the fabrication of single-crystal devices is limited by size, thickness, and interface problems, which makes the development of single-crystal devices inferior to polycrystalline devices, which also limits their future development. Here, several representative optoelectronic applications of perovskite single crystals are introduced, and some existing problems and challenges are discussed. Finally, we outlook the growth mechanism of single crystals and further the prospects of perovskite single crystals in the further field of microelectronics.