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Development of Ion Character Property Relationship (IC-PR) for Removal of 13-Metal Ions by Employing a Novel Green Adsorbent Aerva javanica

The novel Aerva javanica absorbent was applied for the removal of thirteen selected metal ions from a distilled water solution of each metal by the batch adsorption method. The optimization remediation parameters of the metal ions for the batch adsorption approach were developed, which were the init...

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Autores principales: Batool, Fozia, Irfan, Ali, Al-Hussain, Sami A., Al-Farraj, Eida S., Iqbal, Shahid, Akbar, Jamshed, Noreen, Sobia, Akhtar, Taslim, Iqbal, Tunzeel, Zaki, Magdi E. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9741335/
https://www.ncbi.nlm.nih.gov/pubmed/36500307
http://dx.doi.org/10.3390/molecules27238213
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author Batool, Fozia
Irfan, Ali
Al-Hussain, Sami A.
Al-Farraj, Eida S.
Iqbal, Shahid
Akbar, Jamshed
Noreen, Sobia
Akhtar, Taslim
Iqbal, Tunzeel
Zaki, Magdi E. A.
author_facet Batool, Fozia
Irfan, Ali
Al-Hussain, Sami A.
Al-Farraj, Eida S.
Iqbal, Shahid
Akbar, Jamshed
Noreen, Sobia
Akhtar, Taslim
Iqbal, Tunzeel
Zaki, Magdi E. A.
author_sort Batool, Fozia
collection PubMed
description The novel Aerva javanica absorbent was applied for the removal of thirteen selected metal ions from a distilled water solution of each metal by the batch adsorption method. The optimization remediation parameters of the metal ions for the batch adsorption approach were developed, which were the initial concentrations (60 ppm), contact time (60 min) and pH (7). The basic properties of metal ion affected the adsorption results; therefore, 21 properties of metal ions were selected, which are called “descriptors”. The most significant descriptors were selected that were vital for the adsorption results, such as covalent index, polarizability and ion charge. The developed model equation by the descriptors provided more than 80% accuracy in the predicted results. Furthermore, Freundlich and Langmuir adsorption models were also applied on the results. Constants of the Freundlich and Langmuir models were also used for model generation, and the results revealed the importance of a covalent index for the removal phenomenon of metal ions. The current study provided a suitable Ion Character Property Relationship (IC-PR) for the removal of metal ions, and future predictions can be achieved on the proposed adsorbent with significant accuracy. The ecofriendly and cost effective Aerva javanica absorbent in the batch experimental model of the current study predicted that this novel absorbent can be used for the removal of a wide spectrum of heavy metal ions from different sources of waste waters.
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spelling pubmed-97413352022-12-11 Development of Ion Character Property Relationship (IC-PR) for Removal of 13-Metal Ions by Employing a Novel Green Adsorbent Aerva javanica Batool, Fozia Irfan, Ali Al-Hussain, Sami A. Al-Farraj, Eida S. Iqbal, Shahid Akbar, Jamshed Noreen, Sobia Akhtar, Taslim Iqbal, Tunzeel Zaki, Magdi E. A. Molecules Article The novel Aerva javanica absorbent was applied for the removal of thirteen selected metal ions from a distilled water solution of each metal by the batch adsorption method. The optimization remediation parameters of the metal ions for the batch adsorption approach were developed, which were the initial concentrations (60 ppm), contact time (60 min) and pH (7). The basic properties of metal ion affected the adsorption results; therefore, 21 properties of metal ions were selected, which are called “descriptors”. The most significant descriptors were selected that were vital for the adsorption results, such as covalent index, polarizability and ion charge. The developed model equation by the descriptors provided more than 80% accuracy in the predicted results. Furthermore, Freundlich and Langmuir adsorption models were also applied on the results. Constants of the Freundlich and Langmuir models were also used for model generation, and the results revealed the importance of a covalent index for the removal phenomenon of metal ions. The current study provided a suitable Ion Character Property Relationship (IC-PR) for the removal of metal ions, and future predictions can be achieved on the proposed adsorbent with significant accuracy. The ecofriendly and cost effective Aerva javanica absorbent in the batch experimental model of the current study predicted that this novel absorbent can be used for the removal of a wide spectrum of heavy metal ions from different sources of waste waters. MDPI 2022-11-25 /pmc/articles/PMC9741335/ /pubmed/36500307 http://dx.doi.org/10.3390/molecules27238213 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Batool, Fozia
Irfan, Ali
Al-Hussain, Sami A.
Al-Farraj, Eida S.
Iqbal, Shahid
Akbar, Jamshed
Noreen, Sobia
Akhtar, Taslim
Iqbal, Tunzeel
Zaki, Magdi E. A.
Development of Ion Character Property Relationship (IC-PR) for Removal of 13-Metal Ions by Employing a Novel Green Adsorbent Aerva javanica
title Development of Ion Character Property Relationship (IC-PR) for Removal of 13-Metal Ions by Employing a Novel Green Adsorbent Aerva javanica
title_full Development of Ion Character Property Relationship (IC-PR) for Removal of 13-Metal Ions by Employing a Novel Green Adsorbent Aerva javanica
title_fullStr Development of Ion Character Property Relationship (IC-PR) for Removal of 13-Metal Ions by Employing a Novel Green Adsorbent Aerva javanica
title_full_unstemmed Development of Ion Character Property Relationship (IC-PR) for Removal of 13-Metal Ions by Employing a Novel Green Adsorbent Aerva javanica
title_short Development of Ion Character Property Relationship (IC-PR) for Removal of 13-Metal Ions by Employing a Novel Green Adsorbent Aerva javanica
title_sort development of ion character property relationship (ic-pr) for removal of 13-metal ions by employing a novel green adsorbent aerva javanica
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9741335/
https://www.ncbi.nlm.nih.gov/pubmed/36500307
http://dx.doi.org/10.3390/molecules27238213
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