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Synthesis, Characterization, and Structural Analysis of AM[Al(NON(Dipp))(H)(SiH(2)Ph)] (AM = Li, Na, K, Rb, Cs) Compounds, Made Via Oxidative Addition of Phenylsilane to Alkali Metal Aluminyls

[Image: see text] We report the oxidative addition of phenylsilane to the complete series of alkali metal (AM) aluminyls [AM{Al(NON(Dipp))}](2) (AM = Li, Na, K, Rb, and Cs). Crystalline products (1-AM) have been isolated as ether or THF adducts, [AM(L)(n)][Al(NON(Dipp))(H)(SiH(2)Ph)] (AM = Li, Na, K...

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Autores principales: Ballmann, Gerd M., Evans, Matthew J., Gentner, Thomas X., Kennedy, Alan R., Fulton, J. Robin, Coles, Martyn P., Mulvey, Robert E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9749022/
https://www.ncbi.nlm.nih.gov/pubmed/36503245
http://dx.doi.org/10.1021/acs.inorgchem.2c03010
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author Ballmann, Gerd M.
Evans, Matthew J.
Gentner, Thomas X.
Kennedy, Alan R.
Fulton, J. Robin
Coles, Martyn P.
Mulvey, Robert E.
author_facet Ballmann, Gerd M.
Evans, Matthew J.
Gentner, Thomas X.
Kennedy, Alan R.
Fulton, J. Robin
Coles, Martyn P.
Mulvey, Robert E.
author_sort Ballmann, Gerd M.
collection PubMed
description [Image: see text] We report the oxidative addition of phenylsilane to the complete series of alkali metal (AM) aluminyls [AM{Al(NON(Dipp))}](2) (AM = Li, Na, K, Rb, and Cs). Crystalline products (1-AM) have been isolated as ether or THF adducts, [AM(L)(n)][Al(NON(Dipp))(H)(SiH(2)Ph)] (AM = Li, Na, K, Rb, L = Et(2)O, n = 1; AM = Cs, L = THF, n = 2). Further to this series, the novel rubidium rubidiate, [{Rb(THF)(4)}(2)(Rb{Al(NON(Dipp))(H)(SiH(2)Ph)}(2))](+) [Rb{Al(NON(Dipp))(H)(SiH(2)Ph)}(2)](−), was isolated during an attempted recrystallization of Rb[Al(NON(Dipp))(H)(SiH(2)Ph)] from a hexane/THF mixture. Structural and spectroscopic characterizations of the series 1-AM confirm the presence of μ-hydrides that bridge the aluminum and alkali metals (AM), with multiple stabilizing AM···π(arene) interactions to either the Dipp- or Ph-substituents. These products form a complete series of soluble, alkali metal (hydrido) aluminates that present a platform for further reactivity studies.
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spelling pubmed-97490222022-12-15 Synthesis, Characterization, and Structural Analysis of AM[Al(NON(Dipp))(H)(SiH(2)Ph)] (AM = Li, Na, K, Rb, Cs) Compounds, Made Via Oxidative Addition of Phenylsilane to Alkali Metal Aluminyls Ballmann, Gerd M. Evans, Matthew J. Gentner, Thomas X. Kennedy, Alan R. Fulton, J. Robin Coles, Martyn P. Mulvey, Robert E. Inorg Chem [Image: see text] We report the oxidative addition of phenylsilane to the complete series of alkali metal (AM) aluminyls [AM{Al(NON(Dipp))}](2) (AM = Li, Na, K, Rb, and Cs). Crystalline products (1-AM) have been isolated as ether or THF adducts, [AM(L)(n)][Al(NON(Dipp))(H)(SiH(2)Ph)] (AM = Li, Na, K, Rb, L = Et(2)O, n = 1; AM = Cs, L = THF, n = 2). Further to this series, the novel rubidium rubidiate, [{Rb(THF)(4)}(2)(Rb{Al(NON(Dipp))(H)(SiH(2)Ph)}(2))](+) [Rb{Al(NON(Dipp))(H)(SiH(2)Ph)}(2)](−), was isolated during an attempted recrystallization of Rb[Al(NON(Dipp))(H)(SiH(2)Ph)] from a hexane/THF mixture. Structural and spectroscopic characterizations of the series 1-AM confirm the presence of μ-hydrides that bridge the aluminum and alkali metals (AM), with multiple stabilizing AM···π(arene) interactions to either the Dipp- or Ph-substituents. These products form a complete series of soluble, alkali metal (hydrido) aluminates that present a platform for further reactivity studies. American Chemical Society 2022-11-23 2022-12-12 /pmc/articles/PMC9749022/ /pubmed/36503245 http://dx.doi.org/10.1021/acs.inorgchem.2c03010 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Ballmann, Gerd M.
Evans, Matthew J.
Gentner, Thomas X.
Kennedy, Alan R.
Fulton, J. Robin
Coles, Martyn P.
Mulvey, Robert E.
Synthesis, Characterization, and Structural Analysis of AM[Al(NON(Dipp))(H)(SiH(2)Ph)] (AM = Li, Na, K, Rb, Cs) Compounds, Made Via Oxidative Addition of Phenylsilane to Alkali Metal Aluminyls
title Synthesis, Characterization, and Structural Analysis of AM[Al(NON(Dipp))(H)(SiH(2)Ph)] (AM = Li, Na, K, Rb, Cs) Compounds, Made Via Oxidative Addition of Phenylsilane to Alkali Metal Aluminyls
title_full Synthesis, Characterization, and Structural Analysis of AM[Al(NON(Dipp))(H)(SiH(2)Ph)] (AM = Li, Na, K, Rb, Cs) Compounds, Made Via Oxidative Addition of Phenylsilane to Alkali Metal Aluminyls
title_fullStr Synthesis, Characterization, and Structural Analysis of AM[Al(NON(Dipp))(H)(SiH(2)Ph)] (AM = Li, Na, K, Rb, Cs) Compounds, Made Via Oxidative Addition of Phenylsilane to Alkali Metal Aluminyls
title_full_unstemmed Synthesis, Characterization, and Structural Analysis of AM[Al(NON(Dipp))(H)(SiH(2)Ph)] (AM = Li, Na, K, Rb, Cs) Compounds, Made Via Oxidative Addition of Phenylsilane to Alkali Metal Aluminyls
title_short Synthesis, Characterization, and Structural Analysis of AM[Al(NON(Dipp))(H)(SiH(2)Ph)] (AM = Li, Na, K, Rb, Cs) Compounds, Made Via Oxidative Addition of Phenylsilane to Alkali Metal Aluminyls
title_sort synthesis, characterization, and structural analysis of am[al(non(dipp))(h)(sih(2)ph)] (am = li, na, k, rb, cs) compounds, made via oxidative addition of phenylsilane to alkali metal aluminyls
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9749022/
https://www.ncbi.nlm.nih.gov/pubmed/36503245
http://dx.doi.org/10.1021/acs.inorgchem.2c03010
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