Synthesis, Characterization, and Structural Analysis of AM[Al(NON(Dipp))(H)(SiH(2)Ph)] (AM = Li, Na, K, Rb, Cs) Compounds, Made Via Oxidative Addition of Phenylsilane to Alkali Metal Aluminyls

[Image: see text] We report the oxidative addition of phenylsilane to the complete series of alkali metal (AM) aluminyls [AM{Al(NON(Dipp))}](2) (AM = Li, Na, K, Rb, and Cs). Crystalline products (1-AM) have been isolated as ether or THF adducts, [AM(L)(n)][Al(NON(Dipp))(H)(SiH(2)Ph)] (AM = Li, Na, K...

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Detalles Bibliográficos
Autores principales: Ballmann, Gerd M., Evans, Matthew J., Gentner, Thomas X., Kennedy, Alan R., Fulton, J. Robin, Coles, Martyn P., Mulvey, Robert E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9749022/
https://www.ncbi.nlm.nih.gov/pubmed/36503245
http://dx.doi.org/10.1021/acs.inorgchem.2c03010

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