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Oxidative Addition of C–Cl Bonds to a Rh(PONOP) Pincer Complex

[Image: see text] Straightforward procedures for the generation of rhodium(I) κ(Cl)–chlorocarbon complexes of the form [Rh(PONOP-tBu)(κ(Cl)–ClR)][BAr(F)(4)] [R = CH(2)Cl, A; Ph, 1; Cy, 2; tBu, 3; PONOP-tBu = 2,6-bis(di-tert-butylphosphinito)pyridine; Ar(F) = 3,5-bis(trifluoromethyl)phenyl] in soluti...

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Detalles Bibliográficos
Autores principales:	Longcake, Alexandra, Lees, Martin R., Senn, Mark S., Chaplin, Adrian B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9749114/ https://www.ncbi.nlm.nih.gov/pubmed/36533115 http://dx.doi.org/10.1021/acs.organomet.2c00400

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