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Pore Fractal Characteristics of Different Macro-Coal Components and Influence on Adsorption/Desorption: A Case Study in the Huanglong Jurassic Coalfield

[Image: see text] The heterogeneity of pore structure in coal reservoir is extremely complex. In this paper, mercury intrusion porosimetry (MIP) and liquid nitrogen adsorption (LNA) were used to describe pore characteristics of macro-coal components, and the fractal characteristics of pores and thei...

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Autores principales: Ma, Zhuoyuan, Chen, Yue, Ma, Dongmin, Li, Guofu, Li, Weibo, Ji, Yusong, Zheng, Chao, Wang, Liya, Wang, Xin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9749927/
https://www.ncbi.nlm.nih.gov/pubmed/36532108
http://dx.doi.org/10.1021/acsomega.2c04793
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author Ma, Zhuoyuan
Chen, Yue
Ma, Dongmin
Li, Guofu
Li, Weibo
Ji, Yusong
Zheng, Chao
Wang, Liya
Wang, Xin
author_facet Ma, Zhuoyuan
Chen, Yue
Ma, Dongmin
Li, Guofu
Li, Weibo
Ji, Yusong
Zheng, Chao
Wang, Liya
Wang, Xin
author_sort Ma, Zhuoyuan
collection PubMed
description [Image: see text] The heterogeneity of pore structure in coal reservoir is extremely complex. In this paper, mercury intrusion porosimetry (MIP) and liquid nitrogen adsorption (LNA) were used to describe pore characteristics of macro-coal components, and the fractal characteristics of pores and their relationship with adsorption and desorption were discussed. The findings revealed that there were obvious differences in pore characteristics of different macro-coal components at different pore sizes. The total pore volume of vitrain and durain was equivalent, and the total specific surface area was larger than durain, indicating that the micropores in vitrain were more developed, while the macropores in durain were more developed, indicating that the specific surface area was smaller. Fractal results indicated that the pore structure of coal was more complex with the increase of pore diameter. The Da1 and Da2 of vitrain and durain were affected by larger specific surface area and pore volume. The Ds of vitrain increased first and then decreased with the content of vitrinite, while that of durain was the opposite. The relationship between the adsorption capacity of vitrain and fractal dimension Da1 was binomial distribution, and it was positively correlated with Da2. The adsorption capacity of durain samples increased first and then decreased with Da1. With the increase of fractal dimension Ds, the theoretical desorption rate and recovery rate of durain had a downward trend, that is, the more complex the pore structure, the poor the desorption efficiency.
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spelling pubmed-97499272022-12-15 Pore Fractal Characteristics of Different Macro-Coal Components and Influence on Adsorption/Desorption: A Case Study in the Huanglong Jurassic Coalfield Ma, Zhuoyuan Chen, Yue Ma, Dongmin Li, Guofu Li, Weibo Ji, Yusong Zheng, Chao Wang, Liya Wang, Xin ACS Omega [Image: see text] The heterogeneity of pore structure in coal reservoir is extremely complex. In this paper, mercury intrusion porosimetry (MIP) and liquid nitrogen adsorption (LNA) were used to describe pore characteristics of macro-coal components, and the fractal characteristics of pores and their relationship with adsorption and desorption were discussed. The findings revealed that there were obvious differences in pore characteristics of different macro-coal components at different pore sizes. The total pore volume of vitrain and durain was equivalent, and the total specific surface area was larger than durain, indicating that the micropores in vitrain were more developed, while the macropores in durain were more developed, indicating that the specific surface area was smaller. Fractal results indicated that the pore structure of coal was more complex with the increase of pore diameter. The Da1 and Da2 of vitrain and durain were affected by larger specific surface area and pore volume. The Ds of vitrain increased first and then decreased with the content of vitrinite, while that of durain was the opposite. The relationship between the adsorption capacity of vitrain and fractal dimension Da1 was binomial distribution, and it was positively correlated with Da2. The adsorption capacity of durain samples increased first and then decreased with Da1. With the increase of fractal dimension Ds, the theoretical desorption rate and recovery rate of durain had a downward trend, that is, the more complex the pore structure, the poor the desorption efficiency. American Chemical Society 2022-11-17 /pmc/articles/PMC9749927/ /pubmed/36532108 http://dx.doi.org/10.1021/acsomega.2c04793 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Ma, Zhuoyuan
Chen, Yue
Ma, Dongmin
Li, Guofu
Li, Weibo
Ji, Yusong
Zheng, Chao
Wang, Liya
Wang, Xin
Pore Fractal Characteristics of Different Macro-Coal Components and Influence on Adsorption/Desorption: A Case Study in the Huanglong Jurassic Coalfield
title Pore Fractal Characteristics of Different Macro-Coal Components and Influence on Adsorption/Desorption: A Case Study in the Huanglong Jurassic Coalfield
title_full Pore Fractal Characteristics of Different Macro-Coal Components and Influence on Adsorption/Desorption: A Case Study in the Huanglong Jurassic Coalfield
title_fullStr Pore Fractal Characteristics of Different Macro-Coal Components and Influence on Adsorption/Desorption: A Case Study in the Huanglong Jurassic Coalfield
title_full_unstemmed Pore Fractal Characteristics of Different Macro-Coal Components and Influence on Adsorption/Desorption: A Case Study in the Huanglong Jurassic Coalfield
title_short Pore Fractal Characteristics of Different Macro-Coal Components and Influence on Adsorption/Desorption: A Case Study in the Huanglong Jurassic Coalfield
title_sort pore fractal characteristics of different macro-coal components and influence on adsorption/desorption: a case study in the huanglong jurassic coalfield
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9749927/
https://www.ncbi.nlm.nih.gov/pubmed/36532108
http://dx.doi.org/10.1021/acsomega.2c04793
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