On the switching dynamics of epitaxial ferroelectric CeO(2)–HfO(2) thin film capacitors

Epitaxial layers of ferroelectric orthorhombic HfO(2) are frequently investigated as model systems for industrially more relevant polycrystalline films. The recent success in stabilizing the orthorhombic phase in the solid-solution cerium oxide – hafnium oxide system allows detailed investigations of external influences during fabrication. This report analyzes the ferroelectric properties of two thin film capacitors, which were post-deposition annealed in N(2) and O(2) atmospheres to achieve the orthorhombic phase after room temperature deposition. The samples, which exhibit very similar constituent phase, appear identical in conventional polarization-field hysteresis measurements. However, a significant switching speed difference is observed in pristine devices. Continued field cycling reduces the difference. Deeper analysis of switching transients based on the Nucleation Limited Switching model suggests that the O(2) heat treatment atmosphere results in an altered oxygen vacancy profile, which is reverted during ferroelectric cycling. SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1186/s40580-022-00344-4.