A one-pot protocol for iron-catalyzed decarbonylative borylation of aryl and alkyl carboxylic acids

We present a protocol for the eco-friendly synthesis of aryl and alkyl boronic esters from aryl and alkyl carboxylic acids. We describe steps for aryl and alkyl carboxylates preparation. We further detail procedures for the synthesis of borylated products using aryl and alkyl carboxylates through ir...

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Detalles Bibliográficos
Autores principales: Bai, Mei, Geng, Shasha, Chen, Shuo, Liu, Zhengli, Feng, Zhang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2022
Materias:
Protocol
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9763756/
https://www.ncbi.nlm.nih.gov/pubmed/36595923
http://dx.doi.org/10.1016/j.xpro.2022.101909
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author Bai, Mei
Geng, Shasha
Chen, Shuo
Liu, Zhengli
Feng, Zhang
author_facet Bai, Mei
Geng, Shasha
Chen, Shuo
Liu, Zhengli
Feng, Zhang
author_sort Bai, Mei
collection PubMed
description We present a protocol for the eco-friendly synthesis of aryl and alkyl boronic esters from aryl and alkyl carboxylic acids. We describe steps for aryl and alkyl carboxylates preparation. We further detail procedures for the synthesis of borylated products using aryl and alkyl carboxylates through iron-catalyzed decarbonylation at 100°C–130°C, followed by purification of the crude products by flash column chromatography. For complete details on the use and execution of this protocol, please refer to Wen et al. (2022).(1)
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spelling pubmed-97637562022-12-21 A one-pot protocol for iron-catalyzed decarbonylative borylation of aryl and alkyl carboxylic acids Bai, Mei Geng, Shasha Chen, Shuo Liu, Zhengli Feng, Zhang STAR Protoc Protocol We present a protocol for the eco-friendly synthesis of aryl and alkyl boronic esters from aryl and alkyl carboxylic acids. We describe steps for aryl and alkyl carboxylates preparation. We further detail procedures for the synthesis of borylated products using aryl and alkyl carboxylates through iron-catalyzed decarbonylation at 100°C–130°C, followed by purification of the crude products by flash column chromatography. For complete details on the use and execution of this protocol, please refer to Wen et al. (2022).(1) Elsevier 2022-12-09 /pmc/articles/PMC9763756/ /pubmed/36595923 http://dx.doi.org/10.1016/j.xpro.2022.101909 Text en © 2022 The Author(s) https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Protocol
Bai, Mei
Geng, Shasha
Chen, Shuo
Liu, Zhengli
Feng, Zhang
A one-pot protocol for iron-catalyzed decarbonylative borylation of aryl and alkyl carboxylic acids
title A one-pot protocol for iron-catalyzed decarbonylative borylation of aryl and alkyl carboxylic acids
title_full A one-pot protocol for iron-catalyzed decarbonylative borylation of aryl and alkyl carboxylic acids
title_fullStr A one-pot protocol for iron-catalyzed decarbonylative borylation of aryl and alkyl carboxylic acids
title_full_unstemmed A one-pot protocol for iron-catalyzed decarbonylative borylation of aryl and alkyl carboxylic acids
title_short A one-pot protocol for iron-catalyzed decarbonylative borylation of aryl and alkyl carboxylic acids
title_sort one-pot protocol for iron-catalyzed decarbonylative borylation of aryl and alkyl carboxylic acids
topic Protocol
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9763756/
https://www.ncbi.nlm.nih.gov/pubmed/36595923
http://dx.doi.org/10.1016/j.xpro.2022.101909
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