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Modular Synthesis of Highly Substituted 3-Azapyrroles by Rh(II)-Catalyzed N–H Bond Insertion and Cyclodehydration

[Image: see text] A modular synthesis of highly substituted 3-azapyrroles has been developed using a three-step sequence comprising copper-catalyzed alkyne–azide cycloaddition (CuAAC), N–H bond insertion, and cyclodehydration. 1-Sulfonyl-1,2,3-triazoles (1-STs) can be accessed from common alkyne and...

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Detalles Bibliográficos
Autores principales:	Williams, Matthew B., Boyer, Alistair
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9764362/ https://www.ncbi.nlm.nih.gov/pubmed/35503987 http://dx.doi.org/10.1021/acs.joc.2c00434

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