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Experimental and Computational Studies of Ruthenium Complexes Bearing Z-Acceptor Aluminum-Based Phosphine Pincer Ligands

[Image: see text] Reaction of [Ru(C(6)H(4)PPh(2))(2)(Ph(2)PC(6)H(4)AlMe(THF))H] with CO results in clean conversion to the Ru−Al heterobimetallic complex [Ru(AlMePhos)(CO)(3)] (1), where AlMePhos is the novel P–Al(Me)–P pincer ligand (o-Ph(2)PC(6)H(4))(2)AlMe. Under photolytic conditions, 1 reacts w...

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Detalles Bibliográficos
Autores principales:	Isaac, Connie J., Wilson, Cameron I., Burnage, Arron L., Miloserdov, Fedor M., Mahon, Mary F., Macgregor, Stuart A., Whittlesey, Michael K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9768752/ https://www.ncbi.nlm.nih.gov/pubmed/36475641 http://dx.doi.org/10.1021/acs.inorgchem.2c03665

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