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Rate and equilibrium constants for the addition of triazolium salt derived N-heterocyclic carbenes to heteroaromatic aldehydes

Heteroaromatic aldehydes are often used preferentially or exclusively in a range of NHC-catalysed processes that proceed through the generation of a reactive diaminoenol or Breslow Intermediate (BI), with the reason for their unique reactivity currently underexplored. This manuscript reports measure...

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Detalles Bibliográficos
Autores principales:	Duan, Zhuan, Young, Claire M., Zhu, Jiayun, Slawin, Alexandra M. Z., O'Donoghue, AnnMarie C., Smith, Andrew D.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9769090/ https://www.ncbi.nlm.nih.gov/pubmed/36605738 http://dx.doi.org/10.1039/d2sc05704b

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