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Polyoxometalate–peptide hybrid materials: from structure–property relationships to applications
Organo-functionalisation of polyoxometalates (POMs) represents an effective approach to obtain diverse arrays of functional structures and materials, where the introduction of organic moieties into the POM molecules can dramatically change their surface chemistry, charge, polarity, and redox propert...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9769095/ https://www.ncbi.nlm.nih.gov/pubmed/36605748 http://dx.doi.org/10.1039/d2sc05105b |
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author | Soria-Carrera, Héctor Atrián-Blasco, Elena Martín-Rapún, Rafael Mitchell, Scott G. |
author_facet | Soria-Carrera, Héctor Atrián-Blasco, Elena Martín-Rapún, Rafael Mitchell, Scott G. |
author_sort | Soria-Carrera, Héctor |
collection | PubMed |
description | Organo-functionalisation of polyoxometalates (POMs) represents an effective approach to obtain diverse arrays of functional structures and materials, where the introduction of organic moieties into the POM molecules can dramatically change their surface chemistry, charge, polarity, and redox properties. The synergistic combination of POMs and peptides, which perform a myriad of essential roles within cellular biochemistry, including protection and transport in living organisms, leads to functional hybrid materials with unique properties. In this Perspective article, we present the principal synthetic routes to prepare and characterise POM–peptide hybrids, together with a comprehensive description of how their properties – such as redox chemistry, stereochemistry and supramolecular self-assembly – give rise to materials with relevant catalytic, adhesive, and biomedical applications. By presenting the state-of-the-art of the POM–peptide field, we show specifically how emerging chemical approaches can be harnessed to develop tailored POM–peptide materials with synergistic properties for applications in a variety of disciplines. |
format | Online Article Text |
id | pubmed-9769095 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-97690952023-01-04 Polyoxometalate–peptide hybrid materials: from structure–property relationships to applications Soria-Carrera, Héctor Atrián-Blasco, Elena Martín-Rapún, Rafael Mitchell, Scott G. Chem Sci Chemistry Organo-functionalisation of polyoxometalates (POMs) represents an effective approach to obtain diverse arrays of functional structures and materials, where the introduction of organic moieties into the POM molecules can dramatically change their surface chemistry, charge, polarity, and redox properties. The synergistic combination of POMs and peptides, which perform a myriad of essential roles within cellular biochemistry, including protection and transport in living organisms, leads to functional hybrid materials with unique properties. In this Perspective article, we present the principal synthetic routes to prepare and characterise POM–peptide hybrids, together with a comprehensive description of how their properties – such as redox chemistry, stereochemistry and supramolecular self-assembly – give rise to materials with relevant catalytic, adhesive, and biomedical applications. By presenting the state-of-the-art of the POM–peptide field, we show specifically how emerging chemical approaches can be harnessed to develop tailored POM–peptide materials with synergistic properties for applications in a variety of disciplines. The Royal Society of Chemistry 2022-11-16 /pmc/articles/PMC9769095/ /pubmed/36605748 http://dx.doi.org/10.1039/d2sc05105b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Soria-Carrera, Héctor Atrián-Blasco, Elena Martín-Rapún, Rafael Mitchell, Scott G. Polyoxometalate–peptide hybrid materials: from structure–property relationships to applications |
title | Polyoxometalate–peptide hybrid materials: from structure–property relationships to applications |
title_full | Polyoxometalate–peptide hybrid materials: from structure–property relationships to applications |
title_fullStr | Polyoxometalate–peptide hybrid materials: from structure–property relationships to applications |
title_full_unstemmed | Polyoxometalate–peptide hybrid materials: from structure–property relationships to applications |
title_short | Polyoxometalate–peptide hybrid materials: from structure–property relationships to applications |
title_sort | polyoxometalate–peptide hybrid materials: from structure–property relationships to applications |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9769095/ https://www.ncbi.nlm.nih.gov/pubmed/36605748 http://dx.doi.org/10.1039/d2sc05105b |
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