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Heterometallic palladium–iron metal–organic framework as a highly active catalyst for cross-coupling reactions

Palladium-based metal–organic frameworks (Pd-MOFs) are an emerging class of heterogeneous catalysts extremely challenging to achieve due to the facile leaching of palladium and its tendency to be reduced. Herein, Pd(ii) was successfully incorporated in the framework of a MOF denoted as MUV-22 using...

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Autores principales: Miguel-Casañ, Eugenia, Darawsheh, Mohanad D., Fariña-Torres, Víctor, Vitórica-Yrezábal, Iñigo J., Andres-Garcia, Eduardo, Fañanás-Mastral, Martín, Mínguez Espallargas, Guillermo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9769104/
https://www.ncbi.nlm.nih.gov/pubmed/36605746
http://dx.doi.org/10.1039/d2sc05192c
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author Miguel-Casañ, Eugenia
Darawsheh, Mohanad D.
Fariña-Torres, Víctor
Vitórica-Yrezábal, Iñigo J.
Andres-Garcia, Eduardo
Fañanás-Mastral, Martín
Mínguez Espallargas, Guillermo
author_facet Miguel-Casañ, Eugenia
Darawsheh, Mohanad D.
Fariña-Torres, Víctor
Vitórica-Yrezábal, Iñigo J.
Andres-Garcia, Eduardo
Fañanás-Mastral, Martín
Mínguez Espallargas, Guillermo
author_sort Miguel-Casañ, Eugenia
collection PubMed
description Palladium-based metal–organic frameworks (Pd-MOFs) are an emerging class of heterogeneous catalysts extremely challenging to achieve due to the facile leaching of palladium and its tendency to be reduced. Herein, Pd(ii) was successfully incorporated in the framework of a MOF denoted as MUV-22 using a solvent assisted reaction. This stable MOF, with square-octahedron (soc) topology as MIL-127, and a porosity of 710 m(2) g(−1), is highly active, selective, and recyclable for the Suzuki–Miyaura allylation of aryl and alkyl boronates as exemplified with the coupling between cinnamyl bromide and Me-Bpin, a typically reluctant reagent in cross-coupling reactions.
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spelling pubmed-97691042023-01-04 Heterometallic palladium–iron metal–organic framework as a highly active catalyst for cross-coupling reactions Miguel-Casañ, Eugenia Darawsheh, Mohanad D. Fariña-Torres, Víctor Vitórica-Yrezábal, Iñigo J. Andres-Garcia, Eduardo Fañanás-Mastral, Martín Mínguez Espallargas, Guillermo Chem Sci Chemistry Palladium-based metal–organic frameworks (Pd-MOFs) are an emerging class of heterogeneous catalysts extremely challenging to achieve due to the facile leaching of palladium and its tendency to be reduced. Herein, Pd(ii) was successfully incorporated in the framework of a MOF denoted as MUV-22 using a solvent assisted reaction. This stable MOF, with square-octahedron (soc) topology as MIL-127, and a porosity of 710 m(2) g(−1), is highly active, selective, and recyclable for the Suzuki–Miyaura allylation of aryl and alkyl boronates as exemplified with the coupling between cinnamyl bromide and Me-Bpin, a typically reluctant reagent in cross-coupling reactions. The Royal Society of Chemistry 2022-11-22 /pmc/articles/PMC9769104/ /pubmed/36605746 http://dx.doi.org/10.1039/d2sc05192c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Miguel-Casañ, Eugenia
Darawsheh, Mohanad D.
Fariña-Torres, Víctor
Vitórica-Yrezábal, Iñigo J.
Andres-Garcia, Eduardo
Fañanás-Mastral, Martín
Mínguez Espallargas, Guillermo
Heterometallic palladium–iron metal–organic framework as a highly active catalyst for cross-coupling reactions
title Heterometallic palladium–iron metal–organic framework as a highly active catalyst for cross-coupling reactions
title_full Heterometallic palladium–iron metal–organic framework as a highly active catalyst for cross-coupling reactions
title_fullStr Heterometallic palladium–iron metal–organic framework as a highly active catalyst for cross-coupling reactions
title_full_unstemmed Heterometallic palladium–iron metal–organic framework as a highly active catalyst for cross-coupling reactions
title_short Heterometallic palladium–iron metal–organic framework as a highly active catalyst for cross-coupling reactions
title_sort heterometallic palladium–iron metal–organic framework as a highly active catalyst for cross-coupling reactions
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9769104/
https://www.ncbi.nlm.nih.gov/pubmed/36605746
http://dx.doi.org/10.1039/d2sc05192c
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