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Selective oxidation of silanes into silanols with water using [MnBr(CO)(5)] as a precatalyst

The development of earth-abundant catalysts for the selective conversion of silanes to silanols with water as an oxidant generating valuable hydrogen as the only by-product continues to be a challenge. Here, we demonstrate that [MnBr(CO)(5)] is a highly active precatalyst for this reaction, operatin...

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Detalles Bibliográficos
Autores principales: Antico, Emanuele, Leutzsch, Markus, Wessel, Niklas, Weyhermüller, Thomas, Werlé, Christophe, Leitner, Walter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9769106/
https://www.ncbi.nlm.nih.gov/pubmed/36605749
http://dx.doi.org/10.1039/d2sc05959b