Cargando…

Selective oxidation of silanes into silanols with water using [MnBr(CO)(5)] as a precatalyst

The development of earth-abundant catalysts for the selective conversion of silanes to silanols with water as an oxidant generating valuable hydrogen as the only by-product continues to be a challenge. Here, we demonstrate that [MnBr(CO)(5)] is a highly active precatalyst for this reaction, operatin...

Descripción completa

Detalles Bibliográficos
Autores principales:	Antico, Emanuele, Leutzsch, Markus, Wessel, Niklas, Weyhermüller, Thomas, Werlé, Christophe, Leitner, Walter
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9769106/ https://www.ncbi.nlm.nih.gov/pubmed/36605749 http://dx.doi.org/10.1039/d2sc05959b

Ejemplares similares

Conversation from antiferromagnetic MnBr(2) to ferromagnetic Mn(3)Br(8) monolayer with large MAE
por: Hu, Y., et al.
Publicado: (2021)

Synthesis of Cs(3)MnBr(5) Green Phosphors Using an Eco-Friendly Evaporative Crystallization Process
por: Park, Sangwook, et al.
Publicado: (2022)

Dielectric-Optical Switches: Photoluminescent, EPR, and Magnetic Studies on Organic–Inorganic Hybrid (azetidinium)(2)MnBr(4)
por: Rok, Magdalena, et al.
Publicado: (2022)

Molybdenum Alkylidyne Complexes with Tripodal Silanolate Ligands: The Next Generation of Alkyne Metathesis Catalysts
por: Hillenbrand, Julius, et al.
Publicado: (2019)

(1-C5H14N2Br)(2)MnBr(4): A Lead-Free Zero-Dimensional Organic-Metal Halide With Intense Green Photoluminescence
por: Jiang, Xiaomei, et al.
Publicado: (2020)

The Detection and Reactivity of Silanols and Silanes Using Hyperpolarized (29)Si Nuclear Magnetic Resonance
por: Rayner, Peter J., et al.
Publicado: (2020)

Visible Light-Mediated Organoboron-Catalyzed Metal-Free Synthesis of Silanols from Silanes
por: Yang, Jinbo, et al.
Publicado: (2023)

Reduction of Carboxylic Acids to Alcohols via Manganese(I) Catalyzed Hydrosilylation
por: Antico, Emanuele, et al.
Publicado: (2021)

Synthesis and Reactivity of the First Isolated Hydrogen‐Bridged Silanol–Silanolate Anions
por: Weitkamp, Robin F., et al.
Publicado: (2020)

Hydroamination of Aromatic Alkynes to Imines Catalyzed by Pd(II)–Anthraphos Complexes
por: Erken, Christina, et al.
Publicado: (2020)

Synthesis and Characterization of Bipyridyl-(Imidazole)(n) Mn(II) Compounds and Their Evaluation as Potential Precatalysts for Water Oxidation
por: Mu, Ge, et al.
Publicado: (2023)

Systematic Variation of 3d Metal Centers in a Redox-Innocent Ligand Environment: Structures, Electrochemical Properties, and Carbon Dioxide Activation
por: Kinzel, Niklas W., et al.
Publicado: (2021)

Controlling the Product Platform of Carbon Dioxide Reduction: Adaptive Catalytic Hydrosilylation of CO(2) Using a Molecular Cobalt(II) Triazine Complex
por: Cramer, Hanna H., et al.
Publicado: (2020)

Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups
por: Erken, Christina, et al.
Publicado: (2018)

The Influence of Weakly Coordinating Cations on the O−H⋅⋅⋅O(−) Hydrogen Bond of Silanol‐Silanolate Anions
por: Weitkamp, Robin F., et al.
Publicado: (2020)

Organocatalytic DYKAT of Si-Stereogenic Silanes
por: Zhou, Hui, et al.
Publicado: (2023)

tert-Butyldimethylsilanol hemihydrate
por: Barry, Sarah M., et al.
Publicado: (2008)

A Formal Rearrangement of Allylic Silanols
por: Dhokale, Ranjeet A., et al.
Publicado: (2021)

Aminotriazole Mn(I) Complexes as Effective Catalysts for Transfer Hydrogenation of Ketones
por: Martínez‐Ferraté, Oriol, et al.
Publicado: (2018)

Tris(pentafluoroethyl)silanol Derivatives and the Lewis Amphoteric Tris(pentafluoroethyl)silanolate Anion, [Si(C(2)F(5))(3)O](−)
por: Tiessen, Natalia, et al.
Publicado: (2021)

Rapid Surface Functionalization of Hydrogen-Terminated Silicon by Alkyl Silanols
por: Escorihuela, Jorge, et al.
Publicado: (2017)

Homoconjugated Acids as Low Cyclosiloxane-Producing Silanol Polycondensation Catalysts
por: Roberts, John M., et al.
Publicado: (2020)

A Stable Silanol Triad in the Zeolite Catalyst SSZ‐70
por: Schroeder, Christian, et al.
Publicado: (2020)

Transition Metal Complexes as Catalysts for the Electroconversion of CO(2): An Organometallic Perspective
por: Kinzel, Niklas W., et al.
Publicado: (2021)

The Silicon–Hydrogen Exchange Reaction: A Catalytic σ-Bond Metathesis Approach to the Enantioselective Synthesis of Enol Silanes
por: Zhou, Hui, et al.
Publicado: (2020)

Bench-Stable Nickel Precatalysts with Heck-type Activation
por: Weber, Jessica M., et al.
Publicado: (2018)

Silanol: a bifunctional group for peptide synthesis and late-stage functionalization
por: Hu, Qi-Long, et al.
Publicado: (2020)

Concerted Hydrosilylation Catalysis by Silica-Immobilized Cyclic Carbonates and Surface Silanols
por: Hasegawa, Shingo, et al.
Publicado: (2023)

Rhodium(i) complexes derived from tris(isopropyl)-azaphosphatrane—controlling the metal–ligand interplay
por: Chang, Wei-Chieh, et al.
Publicado: (2021)

Boric acid as a precatalyst for BH(3)-catalyzed hydroboration
por: Légaré Lavergne, Julien, et al.
Publicado: (2021)

ZnEt(2) as a Precatalyst for the Addition of Alcohols to Carbodiimides
por: Ramos, Alberto, et al.
Publicado: (2022)

Effective ascorbate-free and photolatent click reactions in water using a photoreducible copper(II)-ethylenediamine precatalyst
por: Beniazza, Redouane, et al.
Publicado: (2015)

A Silicon‐Stereogenic Silanol ‐ (18)O‐Isotope Labeling and Stereogenic Probe Reveals Hidden Stereospecific Water Exchange Reaction
por: Langenohl, Felix, et al.
Publicado: (2022)

Tuning Reconstruction Level of Precatalysts to Design Advanced Oxygen Evolution Electrocatalysts
por: Sun, Hainan, et al.
Publicado: (2021)

The puzzling issue of silica toxicity: are silanols bridging the gaps between surface states and pathogenicity?
por: Pavan, Cristina, et al.
Publicado: (2019)

Nearly free surface silanols are the critical molecular moieties that initiate the toxicity of silica particles
por: Pavan, Cristina, et al.
Publicado: (2020)

A reactive coordinatively saturated Mo(iii) complex: exploiting the hemi-lability of tris(tert-butoxy)silanolate ligands
por: Pucino, Margherita, et al.
Publicado: (2019)

Synthesis of azasilacyclopentenes and silanols via Huisgen cycloaddition-initiated C–H bond insertion cascades
por: Shih, Jiun-Le, et al.
Publicado: (2017)

Application of Hydrophilic Silanol-Based Chemical Grout for Strengthening Damaged Reinforced Concrete Flexural Members
por: Ju, Hyunjin, et al.
Publicado: (2014)

Alkoxy- and Silanol-Functionalized Cage-Type Oligosiloxanes as Molecular Building Blocks to Construct Nanoporous Materials
por: Shimojima, Atsushi, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_qnnqof73p8aa83728vpvq7cgoo