Cargando…
20%-efficient polycrystalline Cd(Se,Te) thin-film solar cells with compositional gradient near the front junction
Bandgap gradient is a proven approach for improving the open-circuit voltages (V(OC)s) in Cu(In,Ga)Se(2) and Cu(Zn,Sn)Se(2) thin-film solar cells, but has not been realized in Cd(Se,Te) thin-film solar cells, a leading thin-film solar cell technology in the photovoltaic market. Here, we demonstrate...
Autores principales: | , , , , , , , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9772316/ https://www.ncbi.nlm.nih.gov/pubmed/36543763 http://dx.doi.org/10.1038/s41467-022-35442-8 |
Sumario: | Bandgap gradient is a proven approach for improving the open-circuit voltages (V(OC)s) in Cu(In,Ga)Se(2) and Cu(Zn,Sn)Se(2) thin-film solar cells, but has not been realized in Cd(Se,Te) thin-film solar cells, a leading thin-film solar cell technology in the photovoltaic market. Here, we demonstrate the realization of a bandgap gradient in Cd(Se,Te) thin-film solar cells by introducing a Cd(O,S,Se,Te) region with the same crystal structure of the absorber near the front junction. The formation of such a region is enabled by incorporating oxygenated CdS and CdSe layers. We show that the introduction of the bandgap gradient reduces the hole density in the front junction region and introduces a small spike in the band alignment between this and the absorber regions, effectively suppressing the nonradiative recombination therein and leading to improved V(OC)s in Cd(Se,Te) solar cells using commercial SnO(2) buffers. A champion device achieves an efficiency of 20.03% with a V(OC) of 0.863 V. |
---|