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Upgrading of Biobased Glycerol to Glycerol Carbonate as a Tool to Reduce the CO(2) Emissions of the Biodiesel Fuel Life Cycle
With regards to oil-based diesel fuel, the adoption of bio-derived diesel fuel was estimated to reduce CO(2) emissions by approximately 75%, considering the whole life cycle. In this paper, we present a novel continuous-flow process able to transfer an equimolar amount of CO(2) (through urea) to gly...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9774724/ https://www.ncbi.nlm.nih.gov/pubmed/36550984 http://dx.doi.org/10.3390/bioengineering9120778 |
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author | Anderlini, Biagio Ughetti, Alberto Cristoni, Emma Forti, Luca Rigamonti, Luca Roncaglia, Fabrizio |
author_facet | Anderlini, Biagio Ughetti, Alberto Cristoni, Emma Forti, Luca Rigamonti, Luca Roncaglia, Fabrizio |
author_sort | Anderlini, Biagio |
collection | PubMed |
description | With regards to oil-based diesel fuel, the adoption of bio-derived diesel fuel was estimated to reduce CO(2) emissions by approximately 75%, considering the whole life cycle. In this paper, we present a novel continuous-flow process able to transfer an equimolar amount of CO(2) (through urea) to glycerol, producing glycerol carbonate. This represents a convenient tool, able to both improve the efficiency of the biodiesel production through the conversion of waste streams into added-value chemicals and to beneficially contribute to the whole carbon cycle. By means of a Design of Experiments approach, the influence of key operating variables on the product yield was studied and statistically modeled. |
format | Online Article Text |
id | pubmed-9774724 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-97747242022-12-23 Upgrading of Biobased Glycerol to Glycerol Carbonate as a Tool to Reduce the CO(2) Emissions of the Biodiesel Fuel Life Cycle Anderlini, Biagio Ughetti, Alberto Cristoni, Emma Forti, Luca Rigamonti, Luca Roncaglia, Fabrizio Bioengineering (Basel) Article With regards to oil-based diesel fuel, the adoption of bio-derived diesel fuel was estimated to reduce CO(2) emissions by approximately 75%, considering the whole life cycle. In this paper, we present a novel continuous-flow process able to transfer an equimolar amount of CO(2) (through urea) to glycerol, producing glycerol carbonate. This represents a convenient tool, able to both improve the efficiency of the biodiesel production through the conversion of waste streams into added-value chemicals and to beneficially contribute to the whole carbon cycle. By means of a Design of Experiments approach, the influence of key operating variables on the product yield was studied and statistically modeled. MDPI 2022-12-06 /pmc/articles/PMC9774724/ /pubmed/36550984 http://dx.doi.org/10.3390/bioengineering9120778 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Anderlini, Biagio Ughetti, Alberto Cristoni, Emma Forti, Luca Rigamonti, Luca Roncaglia, Fabrizio Upgrading of Biobased Glycerol to Glycerol Carbonate as a Tool to Reduce the CO(2) Emissions of the Biodiesel Fuel Life Cycle |
title | Upgrading of Biobased Glycerol to Glycerol Carbonate as a Tool to Reduce the CO(2) Emissions of the Biodiesel Fuel Life Cycle |
title_full | Upgrading of Biobased Glycerol to Glycerol Carbonate as a Tool to Reduce the CO(2) Emissions of the Biodiesel Fuel Life Cycle |
title_fullStr | Upgrading of Biobased Glycerol to Glycerol Carbonate as a Tool to Reduce the CO(2) Emissions of the Biodiesel Fuel Life Cycle |
title_full_unstemmed | Upgrading of Biobased Glycerol to Glycerol Carbonate as a Tool to Reduce the CO(2) Emissions of the Biodiesel Fuel Life Cycle |
title_short | Upgrading of Biobased Glycerol to Glycerol Carbonate as a Tool to Reduce the CO(2) Emissions of the Biodiesel Fuel Life Cycle |
title_sort | upgrading of biobased glycerol to glycerol carbonate as a tool to reduce the co(2) emissions of the biodiesel fuel life cycle |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9774724/ https://www.ncbi.nlm.nih.gov/pubmed/36550984 http://dx.doi.org/10.3390/bioengineering9120778 |
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