Annulation of Perimidines with 5-Alkynylpyrimidines en Route to 7-Formyl-1,3-Diazopyrenes

Unusual rearrangements were shown to accompany Brønsted acid-assisted peri-annulations of 1H-perimidines with 5-alkynylpyrimidines. These transformations take different routes depending on the nature of acetylene precursor, and lead to the formation of 7-formyl-1,3-diazopyrenes.

Detalles Bibliográficos
Autores principales: Shcherbakov, Stanislav V., Aksenov, Alexander V., Vendin, Maksim V., Shcherbakova, Viktoria Yu., Ivanova, Anna Yu., Shcheglov, Maksim O., Ovcharov, Sergei N., Rubin, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9778996/
https://www.ncbi.nlm.nih.gov/pubmed/36555299
http://dx.doi.org/10.3390/ijms232415657
_version_ 1784856500951318528
author Shcherbakov, Stanislav V.
Aksenov, Alexander V.
Vendin, Maksim V.
Shcherbakova, Viktoria Yu.
Ivanova, Anna Yu.
Shcheglov, Maksim O.
Ovcharov, Sergei N.
Rubin, Michael
author_facet Shcherbakov, Stanislav V.
Aksenov, Alexander V.
Vendin, Maksim V.
Shcherbakova, Viktoria Yu.
Ivanova, Anna Yu.
Shcheglov, Maksim O.
Ovcharov, Sergei N.
Rubin, Michael
author_sort Shcherbakov, Stanislav V.
collection PubMed
description Unusual rearrangements were shown to accompany Brønsted acid-assisted peri-annulations of 1H-perimidines with 5-alkynylpyrimidines. These transformations take different routes depending on the nature of acetylene precursor, and lead to the formation of 7-formyl-1,3-diazopyrenes.
format Online
Article
Text
id pubmed-9778996
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-97789962022-12-23 Annulation of Perimidines with 5-Alkynylpyrimidines en Route to 7-Formyl-1,3-Diazopyrenes Shcherbakov, Stanislav V. Aksenov, Alexander V. Vendin, Maksim V. Shcherbakova, Viktoria Yu. Ivanova, Anna Yu. Shcheglov, Maksim O. Ovcharov, Sergei N. Rubin, Michael Int J Mol Sci Article Unusual rearrangements were shown to accompany Brønsted acid-assisted peri-annulations of 1H-perimidines with 5-alkynylpyrimidines. These transformations take different routes depending on the nature of acetylene precursor, and lead to the formation of 7-formyl-1,3-diazopyrenes. MDPI 2022-12-10 /pmc/articles/PMC9778996/ /pubmed/36555299 http://dx.doi.org/10.3390/ijms232415657 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Shcherbakov, Stanislav V.
Aksenov, Alexander V.
Vendin, Maksim V.
Shcherbakova, Viktoria Yu.
Ivanova, Anna Yu.
Shcheglov, Maksim O.
Ovcharov, Sergei N.
Rubin, Michael
Annulation of Perimidines with 5-Alkynylpyrimidines en Route to 7-Formyl-1,3-Diazopyrenes
title Annulation of Perimidines with 5-Alkynylpyrimidines en Route to 7-Formyl-1,3-Diazopyrenes
title_full Annulation of Perimidines with 5-Alkynylpyrimidines en Route to 7-Formyl-1,3-Diazopyrenes
title_fullStr Annulation of Perimidines with 5-Alkynylpyrimidines en Route to 7-Formyl-1,3-Diazopyrenes
title_full_unstemmed Annulation of Perimidines with 5-Alkynylpyrimidines en Route to 7-Formyl-1,3-Diazopyrenes
title_short Annulation of Perimidines with 5-Alkynylpyrimidines en Route to 7-Formyl-1,3-Diazopyrenes
title_sort annulation of perimidines with 5-alkynylpyrimidines en route to 7-formyl-1,3-diazopyrenes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9778996/
https://www.ncbi.nlm.nih.gov/pubmed/36555299
http://dx.doi.org/10.3390/ijms232415657
work_keys_str_mv AT shcherbakovstanislavv annulationofperimidineswith5alkynylpyrimidinesenrouteto7formyl13diazopyrenes
AT aksenovalexanderv annulationofperimidineswith5alkynylpyrimidinesenrouteto7formyl13diazopyrenes
AT vendinmaksimv annulationofperimidineswith5alkynylpyrimidinesenrouteto7formyl13diazopyrenes
AT shcherbakovaviktoriayu annulationofperimidineswith5alkynylpyrimidinesenrouteto7formyl13diazopyrenes
AT ivanovaannayu annulationofperimidineswith5alkynylpyrimidinesenrouteto7formyl13diazopyrenes
AT shcheglovmaksimo annulationofperimidineswith5alkynylpyrimidinesenrouteto7formyl13diazopyrenes
AT ovcharovsergein annulationofperimidineswith5alkynylpyrimidinesenrouteto7formyl13diazopyrenes
AT rubinmichael annulationofperimidineswith5alkynylpyrimidinesenrouteto7formyl13diazopyrenes

Ejemplares similares