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The Phosphinate Group in the Formation of 2D Coordination Polymer with Sm(III) Nodes: X-ray Structural, Electrochemical and Mössbauer Study

A coordination polymer has been synthesized using ferrocene-based ligand-bearing phosphinic groups of 1,1′-ferrocene-diyl-bis(H-phosphinic acid)), and samarium (III). The coordination polymer’s structure was studied by both single-crystal and powder XRD, TG, IR, and Raman analyses. For the first tim...

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Autores principales: Shekurov, Ruslan P., Khrizanforov, Mikhail N., Zagidullin, Almaz A., Zinnatullin, Almaz L., Kholin, Kirill V., Ivshin, Kamil A., Gerasimova, Tatiana P., Sirazieva, Aisylu R., Kataeva, Olga N., Vagizov, Farit G., Miluykov, Vasili A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9779182/
https://www.ncbi.nlm.nih.gov/pubmed/36555210
http://dx.doi.org/10.3390/ijms232415569
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author Shekurov, Ruslan P.
Khrizanforov, Mikhail N.
Zagidullin, Almaz A.
Zinnatullin, Almaz L.
Kholin, Kirill V.
Ivshin, Kamil A.
Gerasimova, Tatiana P.
Sirazieva, Aisylu R.
Kataeva, Olga N.
Vagizov, Farit G.
Miluykov, Vasili A.
author_facet Shekurov, Ruslan P.
Khrizanforov, Mikhail N.
Zagidullin, Almaz A.
Zinnatullin, Almaz L.
Kholin, Kirill V.
Ivshin, Kamil A.
Gerasimova, Tatiana P.
Sirazieva, Aisylu R.
Kataeva, Olga N.
Vagizov, Farit G.
Miluykov, Vasili A.
author_sort Shekurov, Ruslan P.
collection PubMed
description A coordination polymer has been synthesized using ferrocene-based ligand-bearing phosphinic groups of 1,1′-ferrocene-diyl-bis(H-phosphinic acid)), and samarium (III). The coordination polymer’s structure was studied by both single-crystal and powder XRD, TG, IR, and Raman analyses. For the first time, the Mössbauer effect studies were performed on ferrocenyl phosphinate and the polymer based on it. Additionally, the obtained polymer was studied by the method of cyclic and differential pulse voltammetry. It is shown that it has the most positive potential known among ferrocenyl phosphinate-based coordination polymers and metal–organic frameworks. Using the values of the oxidation potential, the polymer was oxidized and the ESR method verified the oxidized Fe(III) form in the solid state. Additionally, the effect of the size of the phosphorus atom substituent of the phosphinate group on the dimension of the resulting coordination compounds is shown.
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spelling pubmed-97791822022-12-23 The Phosphinate Group in the Formation of 2D Coordination Polymer with Sm(III) Nodes: X-ray Structural, Electrochemical and Mössbauer Study Shekurov, Ruslan P. Khrizanforov, Mikhail N. Zagidullin, Almaz A. Zinnatullin, Almaz L. Kholin, Kirill V. Ivshin, Kamil A. Gerasimova, Tatiana P. Sirazieva, Aisylu R. Kataeva, Olga N. Vagizov, Farit G. Miluykov, Vasili A. Int J Mol Sci Article A coordination polymer has been synthesized using ferrocene-based ligand-bearing phosphinic groups of 1,1′-ferrocene-diyl-bis(H-phosphinic acid)), and samarium (III). The coordination polymer’s structure was studied by both single-crystal and powder XRD, TG, IR, and Raman analyses. For the first time, the Mössbauer effect studies were performed on ferrocenyl phosphinate and the polymer based on it. Additionally, the obtained polymer was studied by the method of cyclic and differential pulse voltammetry. It is shown that it has the most positive potential known among ferrocenyl phosphinate-based coordination polymers and metal–organic frameworks. Using the values of the oxidation potential, the polymer was oxidized and the ESR method verified the oxidized Fe(III) form in the solid state. Additionally, the effect of the size of the phosphorus atom substituent of the phosphinate group on the dimension of the resulting coordination compounds is shown. MDPI 2022-12-08 /pmc/articles/PMC9779182/ /pubmed/36555210 http://dx.doi.org/10.3390/ijms232415569 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Shekurov, Ruslan P.
Khrizanforov, Mikhail N.
Zagidullin, Almaz A.
Zinnatullin, Almaz L.
Kholin, Kirill V.
Ivshin, Kamil A.
Gerasimova, Tatiana P.
Sirazieva, Aisylu R.
Kataeva, Olga N.
Vagizov, Farit G.
Miluykov, Vasili A.
The Phosphinate Group in the Formation of 2D Coordination Polymer with Sm(III) Nodes: X-ray Structural, Electrochemical and Mössbauer Study
title The Phosphinate Group in the Formation of 2D Coordination Polymer with Sm(III) Nodes: X-ray Structural, Electrochemical and Mössbauer Study
title_full The Phosphinate Group in the Formation of 2D Coordination Polymer with Sm(III) Nodes: X-ray Structural, Electrochemical and Mössbauer Study
title_fullStr The Phosphinate Group in the Formation of 2D Coordination Polymer with Sm(III) Nodes: X-ray Structural, Electrochemical and Mössbauer Study
title_full_unstemmed The Phosphinate Group in the Formation of 2D Coordination Polymer with Sm(III) Nodes: X-ray Structural, Electrochemical and Mössbauer Study
title_short The Phosphinate Group in the Formation of 2D Coordination Polymer with Sm(III) Nodes: X-ray Structural, Electrochemical and Mössbauer Study
title_sort phosphinate group in the formation of 2d coordination polymer with sm(iii) nodes: x-ray structural, electrochemical and mössbauer study
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9779182/
https://www.ncbi.nlm.nih.gov/pubmed/36555210
http://dx.doi.org/10.3390/ijms232415569
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