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Experimental Investigation of Electro-Mechanical Behavior of Silver-Coated Teflon Fabric-Reinforced Nafion Ionic Polymer Metal Composite with Carbon Nanotubes and Graphene Nanoparticles

Ionic Polymer Metal Composites (IPMCs) are in high demand owing to the ongoing advancements in technology for various applications. New fabrication techniques and a quick retort towards the applied load are the significant reasons for considering IPMCs in smart devices. Here, a Teflon fabric-reinfor...

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Autores principales: Yesaswi, Ch Sridhar, Sahu, Santosh Kumar, Sreekanth, P S Rama
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9781045/
https://www.ncbi.nlm.nih.gov/pubmed/36559862
http://dx.doi.org/10.3390/polym14245497
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author Yesaswi, Ch Sridhar
Sahu, Santosh Kumar
Sreekanth, P S Rama
author_facet Yesaswi, Ch Sridhar
Sahu, Santosh Kumar
Sreekanth, P S Rama
author_sort Yesaswi, Ch Sridhar
collection PubMed
description Ionic Polymer Metal Composites (IPMCs) are in high demand owing to the ongoing advancements in technology for various applications. New fabrication techniques and a quick retort towards the applied load are the significant reasons for considering IPMCs in smart devices. Here, a Teflon fabric-reinforced Nafion (TFRN) membrane is used to create an IPMC. The materials employed as electrodes are silver and nanofillers. The basement membrane, Nafion 438 (N-438), is sandwiched between the electrodes using a chemical decomposition technique. Subsequently, the electromechanical properties (actuation) of the membrane are tested. The micro and molecular structure of the IPMC membrane coated with Silver (Ag), Ag-Carbon nanotubes (CNTs), and Ag-Graphene nanoparticles samples are examined with the help of SEM and X-ray diffraction (XRD). The membrane scratch test is carried out to evaluate the abrasion and wear resistance of the membrane. The lowest coefficient of friction is shown by N438 + Ag + Graphene (0.05), which increased by 300% when compared to a pure N438 membrane. The hydration and tip deflection test were also performed to understand the water uptake percentage. At 90 °C, the highest water uptake was observed for N438 + Ag + Graphene (0.05), which decreased by 60, 42, 23, 14 and 26% when compared to N438, N438 + Ag, N438 + Ag + CNT (0.01), N438 + Ag + CNT (0.05) and N438 + Ag + Graphene (0.01), respectively. A proportional relationship between hydration level and tip deflection is observed and the highest bending performance is observed for the N438 + Ag + Graphene (0.05) membrane.
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spelling pubmed-97810452022-12-24 Experimental Investigation of Electro-Mechanical Behavior of Silver-Coated Teflon Fabric-Reinforced Nafion Ionic Polymer Metal Composite with Carbon Nanotubes and Graphene Nanoparticles Yesaswi, Ch Sridhar Sahu, Santosh Kumar Sreekanth, P S Rama Polymers (Basel) Article Ionic Polymer Metal Composites (IPMCs) are in high demand owing to the ongoing advancements in technology for various applications. New fabrication techniques and a quick retort towards the applied load are the significant reasons for considering IPMCs in smart devices. Here, a Teflon fabric-reinforced Nafion (TFRN) membrane is used to create an IPMC. The materials employed as electrodes are silver and nanofillers. The basement membrane, Nafion 438 (N-438), is sandwiched between the electrodes using a chemical decomposition technique. Subsequently, the electromechanical properties (actuation) of the membrane are tested. The micro and molecular structure of the IPMC membrane coated with Silver (Ag), Ag-Carbon nanotubes (CNTs), and Ag-Graphene nanoparticles samples are examined with the help of SEM and X-ray diffraction (XRD). The membrane scratch test is carried out to evaluate the abrasion and wear resistance of the membrane. The lowest coefficient of friction is shown by N438 + Ag + Graphene (0.05), which increased by 300% when compared to a pure N438 membrane. The hydration and tip deflection test were also performed to understand the water uptake percentage. At 90 °C, the highest water uptake was observed for N438 + Ag + Graphene (0.05), which decreased by 60, 42, 23, 14 and 26% when compared to N438, N438 + Ag, N438 + Ag + CNT (0.01), N438 + Ag + CNT (0.05) and N438 + Ag + Graphene (0.01), respectively. A proportional relationship between hydration level and tip deflection is observed and the highest bending performance is observed for the N438 + Ag + Graphene (0.05) membrane. MDPI 2022-12-15 /pmc/articles/PMC9781045/ /pubmed/36559862 http://dx.doi.org/10.3390/polym14245497 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Yesaswi, Ch Sridhar
Sahu, Santosh Kumar
Sreekanth, P S Rama
Experimental Investigation of Electro-Mechanical Behavior of Silver-Coated Teflon Fabric-Reinforced Nafion Ionic Polymer Metal Composite with Carbon Nanotubes and Graphene Nanoparticles
title Experimental Investigation of Electro-Mechanical Behavior of Silver-Coated Teflon Fabric-Reinforced Nafion Ionic Polymer Metal Composite with Carbon Nanotubes and Graphene Nanoparticles
title_full Experimental Investigation of Electro-Mechanical Behavior of Silver-Coated Teflon Fabric-Reinforced Nafion Ionic Polymer Metal Composite with Carbon Nanotubes and Graphene Nanoparticles
title_fullStr Experimental Investigation of Electro-Mechanical Behavior of Silver-Coated Teflon Fabric-Reinforced Nafion Ionic Polymer Metal Composite with Carbon Nanotubes and Graphene Nanoparticles
title_full_unstemmed Experimental Investigation of Electro-Mechanical Behavior of Silver-Coated Teflon Fabric-Reinforced Nafion Ionic Polymer Metal Composite with Carbon Nanotubes and Graphene Nanoparticles
title_short Experimental Investigation of Electro-Mechanical Behavior of Silver-Coated Teflon Fabric-Reinforced Nafion Ionic Polymer Metal Composite with Carbon Nanotubes and Graphene Nanoparticles
title_sort experimental investigation of electro-mechanical behavior of silver-coated teflon fabric-reinforced nafion ionic polymer metal composite with carbon nanotubes and graphene nanoparticles
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9781045/
https://www.ncbi.nlm.nih.gov/pubmed/36559862
http://dx.doi.org/10.3390/polym14245497
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