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Efficiency Analysis of Fuel Cell Components with Ionic Poly-Arylether Composite Membrane

We use polyethylene glycol as an additive to explore how the hydrogen bonding of this additive changes the properties of SA8 blended sulfonated polyetheretherketone (SPEEK) composite films. We mixed a 5%wt polyethylene glycol solution into a 12.5%wt SA8 solution, and then prepared a film with a tota...

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Autores principales: Wen, Hsin-Yi, Wang, Guang-Hsiang, Chang, Mei-Ying, Huang, Wen-Yao, Hsieh, Tung-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9781248/
https://www.ncbi.nlm.nih.gov/pubmed/36557145
http://dx.doi.org/10.3390/membranes12121238
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author Wen, Hsin-Yi
Wang, Guang-Hsiang
Chang, Mei-Ying
Huang, Wen-Yao
Hsieh, Tung-Li
author_facet Wen, Hsin-Yi
Wang, Guang-Hsiang
Chang, Mei-Ying
Huang, Wen-Yao
Hsieh, Tung-Li
author_sort Wen, Hsin-Yi
collection PubMed
description We use polyethylene glycol as an additive to explore how the hydrogen bonding of this additive changes the properties of SA8 blended sulfonated polyetheretherketone (SPEEK) composite films. We mixed a 5%wt polyethylene glycol solution into a 12.5%wt SA8 solution, and then prepared a film with a total weight of 40g at a ratio of 1:99. The SA8 (PEG) solution was prepared and then mixed with 5%wt SPEEK solution, and a film-forming solution with a total weight of 8g in different mixing ratios was created. Polyethylene glycol (PEG) was mixed into the sulfonated polyarylether polymer SA8 to form physical cross-linking. Therefore, the sulfonated polyether ether ketone SPEEK was mixed in, and it exhibited good thermal stability and dimensional stability. However, there was some decrease in proton conductivity as the proportion of SPEEK increased. Although SPEEK mixed with sulfonated polymer reduces the proton conductivity, the physical cross-linking of PEG can improve the proton conductivity of the composite membrane, and adding SPEEK can not only solve the problem of the high sulfonation film swelling phenomenon, it can also improve the dimensional stability of the film through the hydrogen bonding force of PEG and obtain a composite film with excellent properties.
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spelling pubmed-97812482022-12-24 Efficiency Analysis of Fuel Cell Components with Ionic Poly-Arylether Composite Membrane Wen, Hsin-Yi Wang, Guang-Hsiang Chang, Mei-Ying Huang, Wen-Yao Hsieh, Tung-Li Membranes (Basel) Article We use polyethylene glycol as an additive to explore how the hydrogen bonding of this additive changes the properties of SA8 blended sulfonated polyetheretherketone (SPEEK) composite films. We mixed a 5%wt polyethylene glycol solution into a 12.5%wt SA8 solution, and then prepared a film with a total weight of 40g at a ratio of 1:99. The SA8 (PEG) solution was prepared and then mixed with 5%wt SPEEK solution, and a film-forming solution with a total weight of 8g in different mixing ratios was created. Polyethylene glycol (PEG) was mixed into the sulfonated polyarylether polymer SA8 to form physical cross-linking. Therefore, the sulfonated polyether ether ketone SPEEK was mixed in, and it exhibited good thermal stability and dimensional stability. However, there was some decrease in proton conductivity as the proportion of SPEEK increased. Although SPEEK mixed with sulfonated polymer reduces the proton conductivity, the physical cross-linking of PEG can improve the proton conductivity of the composite membrane, and adding SPEEK can not only solve the problem of the high sulfonation film swelling phenomenon, it can also improve the dimensional stability of the film through the hydrogen bonding force of PEG and obtain a composite film with excellent properties. MDPI 2022-12-07 /pmc/articles/PMC9781248/ /pubmed/36557145 http://dx.doi.org/10.3390/membranes12121238 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Wen, Hsin-Yi
Wang, Guang-Hsiang
Chang, Mei-Ying
Huang, Wen-Yao
Hsieh, Tung-Li
Efficiency Analysis of Fuel Cell Components with Ionic Poly-Arylether Composite Membrane
title Efficiency Analysis of Fuel Cell Components with Ionic Poly-Arylether Composite Membrane
title_full Efficiency Analysis of Fuel Cell Components with Ionic Poly-Arylether Composite Membrane
title_fullStr Efficiency Analysis of Fuel Cell Components with Ionic Poly-Arylether Composite Membrane
title_full_unstemmed Efficiency Analysis of Fuel Cell Components with Ionic Poly-Arylether Composite Membrane
title_short Efficiency Analysis of Fuel Cell Components with Ionic Poly-Arylether Composite Membrane
title_sort efficiency analysis of fuel cell components with ionic poly-arylether composite membrane
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9781248/
https://www.ncbi.nlm.nih.gov/pubmed/36557145
http://dx.doi.org/10.3390/membranes12121238
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