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Absorption Performances of PLA-Montmorillonite Nanocomposites Thin Films in Salisbury and Rozanov Configurations: Influence of Aging and Mechanical Recycling
The present paper aims to address the crucial concern of pollution induced by growing plastic waste and electromagnetic interference (EMI). Nanocomposites combining poly(lactic acid) (PLA) and organo-modified montmorillonite (OMMT) are synthesized and compression molded into thin films. A first set...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9782743/ https://www.ncbi.nlm.nih.gov/pubmed/36557451 http://dx.doi.org/10.3390/mi13122152 |
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author | Sidi Salah, Lakhdar Ouslimani, Nassira Danlée, Yann Huynen, Isabelle |
author_facet | Sidi Salah, Lakhdar Ouslimani, Nassira Danlée, Yann Huynen, Isabelle |
author_sort | Sidi Salah, Lakhdar |
collection | PubMed |
description | The present paper aims to address the crucial concern of pollution induced by growing plastic waste and electromagnetic interference (EMI). Nanocomposites combining poly(lactic acid) (PLA) and organo-modified montmorillonite (OMMT) are synthesized and compression molded into thin films. A first set of samples, referred as virgin, was kept as is, while a second set of samples were photochemically, thermally and hydrolytically aged before mechanical recycling via extruding and second compression molding, resulting in the so-called recycled composite. The electromagnetic (EM) properties with a focus on microwave absorption performances of virgin and recycled samples are compared for various thicknesses and weight concentrations of OMMT in PLA matrix. The EM performances are gauges by Rozanov and Salisbury structures that consist in one- and two-layer stacks of composite films back-coated by a metal foil. Characterization in Rozanov configuration shows an average absorption index over the Ka band of 29.3% and 21.1% for, respectively, virgin and recycled PLA reinforced with 4 wt.% OMMT. An optimization of the film thickness is proposed; up to 61.85% and 80% of absorption with a thickness of 1.4 mm and 3.75 mm, respectively, is reached with a metal back-coated rPLA-4%OMMT film. Characterization in Salisbury configuration gives advantage to the recycled structure with an average absorption of 49.6% for a total thickness of 1.4 mm. The requirements of EMI shielding are met by PLA-OMMT composites with a certain benefit of recycling process on EM performance. |
format | Online Article Text |
id | pubmed-9782743 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-97827432022-12-24 Absorption Performances of PLA-Montmorillonite Nanocomposites Thin Films in Salisbury and Rozanov Configurations: Influence of Aging and Mechanical Recycling Sidi Salah, Lakhdar Ouslimani, Nassira Danlée, Yann Huynen, Isabelle Micromachines (Basel) Article The present paper aims to address the crucial concern of pollution induced by growing plastic waste and electromagnetic interference (EMI). Nanocomposites combining poly(lactic acid) (PLA) and organo-modified montmorillonite (OMMT) are synthesized and compression molded into thin films. A first set of samples, referred as virgin, was kept as is, while a second set of samples were photochemically, thermally and hydrolytically aged before mechanical recycling via extruding and second compression molding, resulting in the so-called recycled composite. The electromagnetic (EM) properties with a focus on microwave absorption performances of virgin and recycled samples are compared for various thicknesses and weight concentrations of OMMT in PLA matrix. The EM performances are gauges by Rozanov and Salisbury structures that consist in one- and two-layer stacks of composite films back-coated by a metal foil. Characterization in Rozanov configuration shows an average absorption index over the Ka band of 29.3% and 21.1% for, respectively, virgin and recycled PLA reinforced with 4 wt.% OMMT. An optimization of the film thickness is proposed; up to 61.85% and 80% of absorption with a thickness of 1.4 mm and 3.75 mm, respectively, is reached with a metal back-coated rPLA-4%OMMT film. Characterization in Salisbury configuration gives advantage to the recycled structure with an average absorption of 49.6% for a total thickness of 1.4 mm. The requirements of EMI shielding are met by PLA-OMMT composites with a certain benefit of recycling process on EM performance. MDPI 2022-12-05 /pmc/articles/PMC9782743/ /pubmed/36557451 http://dx.doi.org/10.3390/mi13122152 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Sidi Salah, Lakhdar Ouslimani, Nassira Danlée, Yann Huynen, Isabelle Absorption Performances of PLA-Montmorillonite Nanocomposites Thin Films in Salisbury and Rozanov Configurations: Influence of Aging and Mechanical Recycling |
title | Absorption Performances of PLA-Montmorillonite Nanocomposites Thin Films in Salisbury and Rozanov Configurations: Influence of Aging and Mechanical Recycling |
title_full | Absorption Performances of PLA-Montmorillonite Nanocomposites Thin Films in Salisbury and Rozanov Configurations: Influence of Aging and Mechanical Recycling |
title_fullStr | Absorption Performances of PLA-Montmorillonite Nanocomposites Thin Films in Salisbury and Rozanov Configurations: Influence of Aging and Mechanical Recycling |
title_full_unstemmed | Absorption Performances of PLA-Montmorillonite Nanocomposites Thin Films in Salisbury and Rozanov Configurations: Influence of Aging and Mechanical Recycling |
title_short | Absorption Performances of PLA-Montmorillonite Nanocomposites Thin Films in Salisbury and Rozanov Configurations: Influence of Aging and Mechanical Recycling |
title_sort | absorption performances of pla-montmorillonite nanocomposites thin films in salisbury and rozanov configurations: influence of aging and mechanical recycling |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9782743/ https://www.ncbi.nlm.nih.gov/pubmed/36557451 http://dx.doi.org/10.3390/mi13122152 |
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