Synthesis of a Triazaisotruxene-Based Porous Organic Polymer and Its Application in Iodine Capture

A new triazaisotruxene-based porous organic polymer (POP) was designed and successfully synthesized by a FeCl(3)-promoted crosslinking reaction. As a result of its porosity and good thermal stability, the designed POP can be utilized as a promising adsorbent for iodine, not only in the gaseous phase...

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Detalles Bibliográficos
Autores principales: Gao, Rong, An, Bohang, Zhou, Cen, Zhang, Xiao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9784556/
https://www.ncbi.nlm.nih.gov/pubmed/36557857
http://dx.doi.org/10.3390/molecules27248722
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author Gao, Rong
An, Bohang
Zhou, Cen
Zhang, Xiao
author_facet Gao, Rong
An, Bohang
Zhou, Cen
Zhang, Xiao
author_sort Gao, Rong
collection PubMed
description A new triazaisotruxene-based porous organic polymer (POP) was designed and successfully synthesized by a FeCl(3)-promoted crosslinking reaction. As a result of its porosity and good thermal stability, the designed POP can be utilized as a promising adsorbent for iodine, not only in the gaseous phase, but also in organic and aqueous solutions. Compared to its triazatruxene (TN) analogue, the ITN-based POP shows equal iodine uptake in the gaseous phase and in hexane solution, and better uptake in aqueous solution.
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spelling pubmed-97845562022-12-24 Synthesis of a Triazaisotruxene-Based Porous Organic Polymer and Its Application in Iodine Capture Gao, Rong An, Bohang Zhou, Cen Zhang, Xiao Molecules Article A new triazaisotruxene-based porous organic polymer (POP) was designed and successfully synthesized by a FeCl(3)-promoted crosslinking reaction. As a result of its porosity and good thermal stability, the designed POP can be utilized as a promising adsorbent for iodine, not only in the gaseous phase, but also in organic and aqueous solutions. Compared to its triazatruxene (TN) analogue, the ITN-based POP shows equal iodine uptake in the gaseous phase and in hexane solution, and better uptake in aqueous solution. MDPI 2022-12-09 /pmc/articles/PMC9784556/ /pubmed/36557857 http://dx.doi.org/10.3390/molecules27248722 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Gao, Rong
An, Bohang
Zhou, Cen
Zhang, Xiao
Synthesis of a Triazaisotruxene-Based Porous Organic Polymer and Its Application in Iodine Capture
title Synthesis of a Triazaisotruxene-Based Porous Organic Polymer and Its Application in Iodine Capture
title_full Synthesis of a Triazaisotruxene-Based Porous Organic Polymer and Its Application in Iodine Capture
title_fullStr Synthesis of a Triazaisotruxene-Based Porous Organic Polymer and Its Application in Iodine Capture
title_full_unstemmed Synthesis of a Triazaisotruxene-Based Porous Organic Polymer and Its Application in Iodine Capture
title_short Synthesis of a Triazaisotruxene-Based Porous Organic Polymer and Its Application in Iodine Capture
title_sort synthesis of a triazaisotruxene-based porous organic polymer and its application in iodine capture
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9784556/
https://www.ncbi.nlm.nih.gov/pubmed/36557857
http://dx.doi.org/10.3390/molecules27248722
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AT anbohang synthesisofatriazaisotruxenebasedporousorganicpolymeranditsapplicationiniodinecapture
AT zhoucen synthesisofatriazaisotruxenebasedporousorganicpolymeranditsapplicationiniodinecapture
AT zhangxiao synthesisofatriazaisotruxenebasedporousorganicpolymeranditsapplicationiniodinecapture

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