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Inducing high exo selectivity in Diels–Alder reaction by dimethylborane substituent: a DFT study
In this work, the role of Lewis acid–base (LAB) interaction on the stereoselectivity of the Diels–Alder (DA) reaction has been studied by DFT in gas and solution (dichloromethane) phases. The calculations were performed at the B3LYP/6-311G++ (d, p) level. Two different series of DA reactions were in...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Nature Publishing Group UK
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9789069/ https://www.ncbi.nlm.nih.gov/pubmed/36564456 http://dx.doi.org/10.1038/s41598-022-26685-y |