Mechanistic Study of Alkyne Insertion into Cu–Al and Au–Al Bonds: A Paradigm Shift for Coinage Metal Chemistry

[Image: see text] In this work, the mechanism of the insertion reaction of 3-hexyne into Cu–Al and Au–Al bonds in M–aluminyl (M = Cu, Au) complexes is computationally elucidated. The mechanism is found to be radical-like, with the Cu–Al and Au–Al bonds acting as nucleophiles toward the alkyne, and p...

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Detalles Bibliográficos
Autores principales: Sorbelli, Diego, Belpassi, Leonardo, Belanzoni, Paola
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9795551/
https://www.ncbi.nlm.nih.gov/pubmed/36493466
http://dx.doi.org/10.1021/acs.inorgchem.2c03713

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9795551/
https://www.ncbi.nlm.nih.gov/pubmed/36493466
http://dx.doi.org/10.1021/acs.inorgchem.2c03713

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