Between Elemental Match and Mismatch: From K(12)Ge(3.5)Sb(6) to Salts of (Ge(2)Sb(2))(2−), (Ge(4)Sb(12))(4−), and (Ge(4)Sb(14))(4−)

The solid mixture “K(2)GeSb” was shown to comprise single‐crystalline K(12)Ge(3.5)Sb(6) (1), a double salt of K(5)[GeSb(3)] with carbonate‐like [GeSb(3)](5−) anions, and the metallic Zintl phase K(2)Ge(1.5). Extraction of 1 with ethane‐1,2‐diamine in the presence of crypt‐222 afforded [K(crypt‐222)]...

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Detalles Bibliográficos
Autores principales: Beuthert, Katrin, Pan, Fuxing, Guggolz, Lukas, Wilson, Robert J., Hempelmann, Jan, Dronskowski, Richard, Dehnen, Stefanie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9796001/
https://www.ncbi.nlm.nih.gov/pubmed/35833677
http://dx.doi.org/10.1002/anie.202207232

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