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Direct Comparison of Subvalent, Polycationic Group 13 Cluster Compounds: Lessons learned on Isoelectronic DMPE Substituted Gallium and Indium Tetracation Salts
The tetracationic, univalent cluster compounds [{M(dmpe)}(4)](4+) (M=Ga, In; dmpe=bis(dimethylphosphino)ethane) were synthesized as their pf salts ([pf](−)=[Al(OR(F))(4)](−); R(F)=C(CF(3))(3)). The four‐membered ring in [{M(dmpe)}(4)](4+) is slightly puckered for M=Ga and almost square planar for M=...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9796046/ https://www.ncbi.nlm.nih.gov/pubmed/35695015 http://dx.doi.org/10.1002/chem.202201369 |