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Hydrogen Activation by Frustrated and Not So Frustrated Lewis Pairs Based on Pyramidal Lewis Acid 9-Boratriptycene: A Computational Study
[Image: see text] Structural features and reactivity of frustrated Lewis pairs (FLPs) formed by pyramidal group 13 Lewis acids based on 9-bora and 9-alatriptycene and bulky phosphines P(t)Bu(3), PPh(3), and PCy(3) are considered at the M06-2X/def2-TZVP level of theory. Classic FLP is formed only in...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9798527/ https://www.ncbi.nlm.nih.gov/pubmed/36591180 http://dx.doi.org/10.1021/acsomega.2c06836 |