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Insight into the LED-assisted deposition of platinum nanoparticles on the titania surface: understanding the effect of LEDs

This paper proposes a novel LED-assisted deposition of platinum nanoparticles on the titania surface. For the first time, this process was supported by a UV-LED solution. We used two light sources with different wavelengths (λ(max) = 365 and 395 nm), and power (P = 1, 5, and 10 W) because the photod...

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Detalles Bibliográficos
Autores principales: Kubiak, Adam, Varma, Naisargi, Sikorski, Marek
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9800554/
https://www.ncbi.nlm.nih.gov/pubmed/36581762
http://dx.doi.org/10.1038/s41598-022-27232-5
Descripción
Sumario:This paper proposes a novel LED-assisted deposition of platinum nanoparticles on the titania surface. For the first time, this process was supported by a UV-LED solution. We used two light sources with different wavelengths (λ(max) = 365 and 395 nm), and power (P = 1, 5, and 10 W) because the photodeposition process based on LEDs has not been defined. The TiO(2)–Pt material was discovered to be nano-crystalline anatase particles with nano-platinum particles deposited on the surface of titanium dioxide. Furthermore, the luminescence intensity decreased when Pt was added to TiO(2), indicating that charge carrier recombination was reduced. The spectra matching of the photocatalyst and LED reactor was performed for the first time in this work. We proposed a convenient LED reactor that focused light in the range of 350–450 nm, allowing us to effectively use photo-oxidative properties of TiO(2)–Pt materials in the process of removing 4-chlorophenol. In the presented work, the LED light source plays a dual role. They first induce the platinum photodeposition process, before becoming an important component of tailored photoreactors, which is an important innovative aspect of this research.