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Reversible Oxidative Addition of Zinc Hydride at a Gallium(I)‐Centre: Labile Mono‐ and Bis(hydridogallyl)zinc Complexes
In the presence of TMEDA (N,N,N’,N’‐tetramethylethylenediamine), partially deaggregated zinc dihydride as hydrocarbon suspensions react with the gallium(I) compound [(BDI)Ga] (I, BDI={HC(C(CH(3))N(2,6‐iPr(2)‐C(6)H(3)))(2)}(−)) by formal oxidative addition of a Zn−H bond to the gallium(I) centre. Dis...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804236/ https://www.ncbi.nlm.nih.gov/pubmed/35819049 http://dx.doi.org/10.1002/chem.202201480 |