B(C(6)F(5))(3)‐Catalyzed E‐Selective Isomerization of Alkenes

Herein, we report the B(C(6)F(5))(3)‐catalyzed E‐selective isomerization of alkenes. The transition‐metal‐free method is applicable across a diverse array of readily accessible substrates, giving access to a broad range of synthetically useful products containing versatile stereodefined internal alk...

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Detalles Bibliográficos
Autores principales: Kustiana, Betty A., Elsherbeni, Salma A., Linford‐Wood, Thomas G., Melen, Rebecca L., Grayson, Matthew N., Morrill, Louis C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804281/
https://www.ncbi.nlm.nih.gov/pubmed/35943082
http://dx.doi.org/10.1002/chem.202202454
Descripción
Sumario:Herein, we report the B(C(6)F(5))(3)‐catalyzed E‐selective isomerization of alkenes. The transition‐metal‐free method is applicable across a diverse array of readily accessible substrates, giving access to a broad range of synthetically useful products containing versatile stereodefined internal alkenes. The reaction mechanism was investigated by using synthetic and computational methods.

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