B(C(6)F(5))(3)‐Catalyzed E‐Selective Isomerization of Alkenes

Herein, we report the B(C(6)F(5))(3)‐catalyzed E‐selective isomerization of alkenes. The transition‐metal‐free method is applicable across a diverse array of readily accessible substrates, giving access to a broad range of synthetically useful products containing versatile stereodefined internal alk...

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Detalles Bibliográficos
Autores principales: Kustiana, Betty A., Elsherbeni, Salma A., Linford‐Wood, Thomas G., Melen, Rebecca L., Grayson, Matthew N., Morrill, Louis C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804281/
https://www.ncbi.nlm.nih.gov/pubmed/35943082
http://dx.doi.org/10.1002/chem.202202454
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author Kustiana, Betty A.
Elsherbeni, Salma A.
Linford‐Wood, Thomas G.
Melen, Rebecca L.
Grayson, Matthew N.
Morrill, Louis C.
author_facet Kustiana, Betty A.
Elsherbeni, Salma A.
Linford‐Wood, Thomas G.
Melen, Rebecca L.
Grayson, Matthew N.
Morrill, Louis C.
author_sort Kustiana, Betty A.
collection PubMed
description Herein, we report the B(C(6)F(5))(3)‐catalyzed E‐selective isomerization of alkenes. The transition‐metal‐free method is applicable across a diverse array of readily accessible substrates, giving access to a broad range of synthetically useful products containing versatile stereodefined internal alkenes. The reaction mechanism was investigated by using synthetic and computational methods.
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spelling pubmed-98042812023-01-03 B(C(6)F(5))(3)‐Catalyzed E‐Selective Isomerization of Alkenes Kustiana, Betty A. Elsherbeni, Salma A. Linford‐Wood, Thomas G. Melen, Rebecca L. Grayson, Matthew N. Morrill, Louis C. Chemistry Research Articles Herein, we report the B(C(6)F(5))(3)‐catalyzed E‐selective isomerization of alkenes. The transition‐metal‐free method is applicable across a diverse array of readily accessible substrates, giving access to a broad range of synthetically useful products containing versatile stereodefined internal alkenes. The reaction mechanism was investigated by using synthetic and computational methods. John Wiley and Sons Inc. 2022-09-01 2022-11-11 /pmc/articles/PMC9804281/ /pubmed/35943082 http://dx.doi.org/10.1002/chem.202202454 Text en © 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Articles
Kustiana, Betty A.
Elsherbeni, Salma A.
Linford‐Wood, Thomas G.
Melen, Rebecca L.
Grayson, Matthew N.
Morrill, Louis C.
B(C(6)F(5))(3)‐Catalyzed E‐Selective Isomerization of Alkenes
title B(C(6)F(5))(3)‐Catalyzed E‐Selective Isomerization of Alkenes
title_full B(C(6)F(5))(3)‐Catalyzed E‐Selective Isomerization of Alkenes
title_fullStr B(C(6)F(5))(3)‐Catalyzed E‐Selective Isomerization of Alkenes
title_full_unstemmed B(C(6)F(5))(3)‐Catalyzed E‐Selective Isomerization of Alkenes
title_short B(C(6)F(5))(3)‐Catalyzed E‐Selective Isomerization of Alkenes
title_sort b(c(6)f(5))(3)‐catalyzed e‐selective isomerization of alkenes
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804281/
https://www.ncbi.nlm.nih.gov/pubmed/35943082
http://dx.doi.org/10.1002/chem.202202454
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